scholarly journals Boron- and phosphorus-doped silicon germanium alloy nanocrystals—Nonthermal plasma synthesis and gas-phase thin film deposition

APL Materials ◽  
2014 ◽  
Vol 2 (2) ◽  
pp. 022104 ◽  
Author(s):  
David J. Rowe ◽  
Uwe R. Kortshagen
Author(s):  
Gregory F. Pach ◽  
Fernando Urias-Cordero ◽  
Sadegh Yazdi ◽  
Nathan R Neale

2014 ◽  
Vol 2 (28) ◽  
pp. 5644-5650 ◽  
Author(s):  
Takashi Kanno ◽  
Minoru Fujii ◽  
Hiroshi Sugimoto ◽  
Kenji Imakita

Si1−xGex alloy nanocrystals potentially have superior properties compared to Si nanocrystals such as an enhanced absorption cross-section and wider controllability of the band gap energy.


1985 ◽  
Vol 54 ◽  
Author(s):  
D. W. Squire ◽  
C. S. Dulcey ◽  
M. C. Lin

ABSTRACTThe low pressure pyrolysis of alkylmetals on resistively heated substrates was studied using multiphoton and electron ionization mass analysis. The activation energy for the production of gas phase methyl radicals from the decomposition of trimethylgallium under single collision conditions was found to be 26 ± 3 kcal/mol, which is to be compared to 13 ± 2 kcal/mol previously observed for trimethylaluminum. No evidence could be found for any surface radical reactions leading to the production of CH4 or C2H6. A proposed deposition mechanism accounting for these observations was tested by pyrolyzing trimethylgallium in the presence of hydrazine. No change in methyl signal was observed, supporting the theory that radical reactions do not occur on the surface under the conditions employed.


2015 ◽  
Vol 3 (41) ◽  
pp. 10898-10906 ◽  
Author(s):  
Mewlude Imam ◽  
Konstantin Gaul ◽  
Andreas Stegmüller ◽  
Carina Höglund ◽  
Jens Jensen ◽  
...  

We present triethylboron (TEB) as a single-source precursor for chemical vapor deposition (CVD) of BxC thin films and study its gas phase chemistry under CVD conditions by quantum chemical calculations.


Author(s):  
R. F. Schneidmiller ◽  
W. F. Thrower ◽  
C. Ang

Solid state materials in the form of thin films have found increasing structural and electronic applications. Among the multitude of thin film deposition techniques, the radio frequency induced plasma sputtering has gained considerable utilization in recent years through advances in equipment design and process improvement, as well as the discovery of the versatility of the process to control film properties. In our laboratory we have used the scanning electron microscope extensively in the direct and indirect characterization of sputtered films for correlation with their physical and electrical properties.Scanning electron microscopy is a powerful tool for the examination of surfaces of solids and for the failure analysis of structural components and microelectronic devices.


Author(s):  
M. Grant Norton ◽  
C. Barry Carter

Pulsed-laser ablation has been widely used to produce high-quality thin films of YBa2Cu3O7-δ on a range of substrate materials. The nonequilibrium nature of the process allows congruent deposition of oxides with complex stoichiometrics. In the high power density regime produced by the UV excimer lasers the ablated species includes a mixture of neutral atoms, molecules and ions. All these species play an important role in thin-film deposition. However, changes in the deposition parameters have been shown to affect the microstructure of thin YBa2Cu3O7-δ films. The formation of metastable configurations is possible because at the low substrate temperatures used, only shortrange rearrangement on the substrate surface can occur. The parameters associated directly with the laser ablation process, those determining the nature of the process, e g. thermal or nonthermal volatilization, have been classified as ‘primary parameters'. Other parameters may also affect the microstructure of the thin film. In this paper, the effects of these ‘secondary parameters' on the microstructure of YBa2Cu3O7-δ films will be discussed. Examples of 'secondary parameters' include the substrate temperature and the oxygen partial pressure during deposition.


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