Membrane formation by preferential solvation of ions in mixture of water, 3-methylpyridine, and sodium tetraphenylborate

2013 ◽  
Vol 139 (23) ◽  
pp. 234905 ◽  
Author(s):  
Koichiro Sadakane ◽  
Michihiro Nagao ◽  
Hitoshi Endo ◽  
Hideki Seto
Keyword(s):  
Preferential Solvation ◽  
Sodium Tetraphenylborate ◽  
Membrane Formation ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1986 ◽  
Vol 150 (1) ◽  
pp. 113-122 ◽  
Author(s):  
Dip Singh Gill ◽  
Suvarcha Chauhan ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents II

1983 ◽  
Vol 136 (136) ◽  
pp. 117-122 ◽  
Author(s):  
Dip Singh Gill ◽  
Reeta Nording
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1984 ◽  
Vol 140 (2) ◽  
pp. 139-148 ◽  
Author(s):  
Dip Singh Gill ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1984 ◽  
Vol 140 (2) ◽  
pp. 149-156 ◽  
Author(s):  
Dip Singh Gill ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1983 ◽  
Vol 134 (2) ◽  
pp. 205-214 ◽  
Author(s):  
Dip Singh Gill ◽  
Jagir Singh Cheema
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

scholarly journals Viscometric Studies of Ion Solvation of Some Alkali Metal Salts in 2-Aminoethanol + N,N-Dimethylacetamide Binary Mixtures at 298.15 K and 308.15 K

2021 ◽  
Vol 33 (12) ◽  
pp. 2924-2928
Author(s):  
Suresh Kumar ◽  
Hardeep Anand ◽  
Narender Singh
Keyword(s):  
Binary Mixtures ◽  
Preferential Solvation ◽  
Sodium Perchlorate ◽  
Ammonium Thiocyanate ◽  
Lithium Perchlorate ◽  
Potassium Thiocyanate ◽  
Solvent System ◽  
Viscosity Data ◽  
Solvation Of Ions ◽  
B Coefficients

Densities (ρ) and viscosities (η) of lithium perchlorate (LiClO4), sodium perchlorate (NaClO4), potassium thiocyanate (KSCN), tetrabutyl-ammonium thiocyanate (Bu4NSCN), tetrabutylammonium tetraphenylborate (Bu4NBPh4) and tetrabutylammonium perchlorate (Bu4NClO4) were measured in binary mixed solutions of 2-aminoethanol (AE) and N,N-dimethylacetamide (DMA) containing 25, 50, 60, 80 and 100 mol % DMA in the concentration range (3-500) ×10-4 mol kg-1 at 298.15 K and 308.15 K temperatures. The density and viscosity data were analyzed using the Jones-Dole equation in the form ηr = 1 + A(C1/2) + BC for unassociated electrolytes and viscosity A and B-coefficients were obtained from the plots of of ηr – 1/C1/2 versus C1/2. The A-coefficients obtained from the analysis of Jones-Dole equation are positive as well as negative. The positive values indicate the solvation of ions in solutions of binary mixtures (AE + DMA) especially in 50 and 60 mol% DMA. The viscosity B-coefficients of all these electrolytes were positive and large in case of cations and were split into their respective ionic (B±) coefficient values using a method reported by Gill and Sharma. The viscosity B-coefficients values were increasing with the increase increasing DMA composition in the binary mixed solvent system of AE + DMA but decreasing with increasing temperature from 298.15 K to 308.15 K. The obtained results indicate about the preferential solvation of ions i.e. Li+, Na+, K+, Bu4N+ and Ph4B– ions and poor solvation of ClO4 – and SCN– ions. The results also revealed that these interactions get weaker with increase in temperature. The resulting B-coefficients and its dependence of temperature provide useful information regarding changes in the solvent structure.

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