scholarly journals Shock response of single crystal and nanocrystalline pentaerythritol tetranitrate: Implications to hotspot formation in energetic materials

2013 ◽  
Vol 139 (16) ◽  
pp. 164704 ◽  
Author(s):  
Y. Cai ◽  
F. P. Zhao ◽  
Q. An ◽  
H. A. Wu ◽  
W. A. Goddard ◽  
...  
2010 ◽  
Vol 638-642 ◽  
pp. 1059-1064
Author(s):  
Kunihito Nagayama ◽  
Yasuhito Mori

Polymer materials have widespread applications in various situations for structural materials by themselves as well as by combining with other materials such as carbon fiber. Some of them are also candidates for energetic materials in space applications.[1] Due to their general use, shock response of them has attracted attention for many researchers.[2-4] One of the striking characteristics of the dynamic response of them is that stress and/or particle velocity profile has a relaxation structure of s range.[5, 6]


2011 ◽  
Vol 115 (14) ◽  
pp. 6893-6901 ◽  
Author(s):  
Edward D. Aluker ◽  
Alexander G. Krechetov ◽  
Anatoliy Y. Mitrofanov ◽  
Denis R. Nurmukhametov ◽  
Maija M. Kuklja

1992 ◽  
Vol 296 ◽  
Author(s):  
J. Covino ◽  
S. A. Finnegan ◽  
O. E. R Heimdahl ◽  
A. J. Lindfors ◽  
J. K. Pringle

AbstractThis paper discusses experimental techniques and modelling tools used to characterize energetic solids subjected to dynamic deformation and shock. Critical experiments have been designed to study shock response and impact sensitivity of energetic materials. For example, a simplified two dimensional experiment has been developed to study the critical phenomena involved in delayed detonation reactions (XDT). In addition, wedge tests are used to obtain equation-of-state data. Coupled with hydrocodes, these experiments give us an in-depth understanding of the response of energetic materials subjected to shock loading. A coupled methodology using both experimental and modelling tools is presented. Consisting of three parts, it addresses all possible responses to fragment impact. The three parts are: (1) Fragment impact modelling (hydrocodes and empirically based codes); (2) Experiments to obtain accurate data for predicting prompt detonation; and (3) Tests with planar rocket motor models to explore mechanisms related to bum reaction thresholds and degree of violence. This methodology is currently being used in weapon design and munitions hazard assessments.


2005 ◽  
Vol 896 ◽  
Author(s):  
Omkar Nafday ◽  
Brandon Weeks ◽  
Jason Haaheim ◽  
Ray Eby

AbstractRecently there has been a focused effort to develop reliable nanoscopic writing and reading capabilities. Dip-pen nanolithography (DPN) has emerged as a convenient method to deliver nanoscale materials onto a substrate by leveraging scanning probe microscopy capability. A new application for the DPN method is the field of microdetonics which is the microscale decomposition and study of reactions of explosives. Results are presented for patterning pentaerythritol tetranitrate (PETN) and cyclotetramethylene tetranitramine (HMX) on silicon and mica substrates. The ultimate goal is to pattern both energetic materials in nanoscale registry and investigate their reaction and decomposition at the nanoscale due to heating or shock initiation. In addition to patterning of high explosives, a discussion on the effect of surface energy on patterning rates is investigated. This knowledge will be applicable to inks beyond high explosives.


2014 ◽  
Vol 116 (21) ◽  
pp. 213506 ◽  
Author(s):  
B. Li ◽  
L. Wang ◽  
J. C. E ◽  
H. H. Ma ◽  
S. N. Luo

1991 ◽  
Vol 70 (7) ◽  
pp. 3572-3587 ◽  
Author(s):  
J. J. Dick ◽  
R. N. Mulford ◽  
W. J. Spencer ◽  
D. R. Pettit ◽  
E. Garcia ◽  
...  

2012 ◽  
Vol 2 (3) ◽  
Author(s):  
Gengxin Zhang ◽  
Brandon Weeks ◽  
Xin Zhang

AbstractThe energy output performance and thermal stability of organic energetic materials have a strong dependence on the porosity, particle morphology, and micro-scale crystal structure. This paper reviews the growth habit of pure pentaerythritol tetranitrate (PETN) crystals and the effect of metal impurities on microcrystal morphology of PETN films. The pure crystal growth shows that PETN molecules diffuse on the surface and nucleate in a two-dimensional layer-by-layer fashion; the final structure is controlled by the deposition flux. Also, the effect of metal cation impurities has a strong impact on the thermal stability and crystal structure, and is dependent on the doping level.


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