Lattice model of living polymerization. III. Evidence for particle clustering from phase separation properties and “rounding” of the dynamical clustering transition

2000 ◽  
Vol 113 (1) ◽  
pp. 434-446 ◽  
Author(s):  
Jacek Dudowicz ◽  
Karl F. Freed ◽  
Jack F. Douglas
Keyword(s):  
Phase Separation ◽  
Lattice Model ◽  
Living Polymerization ◽  
Particle Clustering

scholarly journals Correction to “A Lattice Model of Charge-Pattern-Dependent Polyampholyte Phase Separation”

2018 ◽  
Vol 122 (33) ◽  
pp. 8111-8111 ◽  
Author(s):  
Suman Das ◽  
Adam Eisen ◽  
Yi-Hsuan Lin ◽  
Hue Sun Chan
Keyword(s):  
Phase Separation ◽  
Lattice Model

scholarly journals Phase separation in a lattice model of a superconductor with pair hopping

2012 ◽  
Vol 24 (21) ◽  
pp. 215601 ◽  
Author(s):  
Konrad Kapcia ◽  
Stanisław Robaszkiewicz ◽  
Roman Micnas
Keyword(s):  
Phase Separation ◽  
Lattice Model ◽  
Pair Hopping

Lattice model of living polymerization. II. Interplay between polymerization and phase stability

2000 ◽  
Vol 112 (2) ◽  
pp. 1002-1010 ◽  
Author(s):  
Jacek Dudowicz ◽  
Karl F. Freed ◽  
Jack F. Douglas
Keyword(s):  
Phase Stability ◽  
Lattice Model ◽  
Living Polymerization

scholarly journals A Lattice Model of Charge-Pattern-Dependent Polyampholyte Phase Separation

2018 ◽  
Vol 122 (21) ◽  
pp. 5418-5431 ◽  
Author(s):  
Suman Das ◽  
Adam Eisen ◽  
Yi-Hsuan Lin ◽  
Hue Sun Chan
Keyword(s):  
Phase Separation ◽  
Lattice Model

Lattice model of living polymerization. I. Basic thermodynamic properties

1999 ◽  
Vol 111 (15) ◽  
pp. 7116-7130 ◽  
Author(s):  
Jacek Dudowicz ◽  
Karl F. Freed ◽  
Jack F. Douglas
Keyword(s):  
Thermodynamic Properties ◽  
Lattice Model ◽  
Living Polymerization

Modelling Microstructiure in Materials that Contain Anisotropic Particles

1989 ◽  
Vol 175 ◽  
Author(s):  
Christopher Viney ◽  
Larry A. Chick
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Phase Separation ◽  
Thermodynamic Analysis ◽  
Crystalline Phase ◽  
Lattice Model ◽  
Liquid Crystalline ◽  
Anisotropic Particles ◽  
Starting Point ◽  
Evolution Of Microstructure

AbstractThe spontaneous alignment of molecules in liquid crystalline solutions is characteristic of other materials that contain rodlike particles. We are developing a model to predict the evolution of microstructure in these systems. Its starting point is Flory's thermodynamic analysis of liquid crystalline phase separation. Our preferred method dispenses with the traditional lattice model in favor of a Monte Carlo simulation to calculate entropy. Some advantages and consequences of our approach are explored in this paper

Preparation of Macroporous Poly(divinylbenzene) Gels via Living Radical Polymerization

2008 ◽  
Vol 1134 ◽  
Author(s):  
Joji Hasegawa ◽  
Kazuyoshi Kanamori ◽  
Kazuki Nakanishi ◽  
Teiichi Hanada ◽  
Shigeru Yamago
Keyword(s):  
Phase Separation ◽  
Radical Polymerization ◽  
Spinodal Decomposition ◽  
Living Polymerization ◽  
Living Radical Polymerization ◽  
Polymerization Reaction ◽  
Bicontinuous Structure ◽  
Polymerization Induced Phase Separation ◽  
Micrometer Scale ◽  
Transient Structure

AbstractMacroporous cross-linked polymeric dried gels have been obtained by inducing phase separation in a homogeneous poly(divinylbenzene) (PDVB) network formed by organotellurium-mediated living radical polymerization (TERP). The living polymerization reaction of DVB with the coexistence of a non-reactive polymeric agent, poly(dimethylsiloxane) (PDMS), in solvent 1,3,5-trimethylbenzene (TMB) resulted in polymerization-induced phase separation (spinodal decomposition), and the transient structure of spinodal decomposition has been frozen by gelation. Well-defined macroporous monolithic dried gels with bicontinuous structure in the micrometer scale are obtained after removing PDMS and TMB by simple washing and drying. The properties of the macropores have been controlled by changing starting composition.

scholarly journals Three-dimensional patchy lattice model: Ring formation and phase separation

2014 ◽  
Vol 140 (4) ◽  
pp. 044905 ◽  
Author(s):  
J. M. Tavares ◽  
N. G. Almarza ◽  
M. M. Telo da Gama
Keyword(s):  
Phase Separation ◽  
Lattice Model ◽  
Three Dimensional ◽  
Ring Formation
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