Effects from A-site substitution on morphotropic phase boundary and phonon modes of (Pb1–1.5xLax)(Zr0.42Sn0.40Ti0.18)O3 ceramics by temperature dependent Raman spectroscopy

2013 ◽  
Vol 114 (4) ◽  
pp. 043507 ◽  
Keyword(s):  
Raman Spectroscopy ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Phonon Modes ◽  
Temperature Dependent ◽  
A Site

scholarly journals Study of Thermometry in Two-Dimensional Sb2Te3 from Temperature-Dependent Raman Spectroscopy

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Manavendra P. Singh ◽  
Manab Mandal ◽  
K. Sethupathi ◽  
M. S. Ramachandra Rao ◽  
Pramoda K. Nayak
Keyword(s):  
Thermal Conductivity ◽  
Raman Spectroscopy ◽  
Temperature Coefficient ◽  
Heat Dissipation ◽  
Peak Position ◽  
Two Dimensional ◽  
Phonon Modes ◽  
Temperature Dependent ◽  
Excellent Candidate ◽  
High Figure

AbstractDiscovery of two-dimensional (2D) topological insulators (TIs) demonstrates tremendous potential in the field of thermoelectric since the last decade. Here, we have synthesized 2D TI, Sb2Te3 of various thicknesses in the range 65–400 nm using mechanical exfoliation and studied temperature coefficient in the range 100–300 K using micro-Raman spectroscopy. The temperature dependence of the peak position and line width of phonon modes have been analyzed to determine the temperature coefficient, which is found to be in the order of 10–2 cm−1/K, and it decreases with a decrease in Sb2Te3 thickness. Such low-temperature coefficient would favor to achieve a high figure of merit (ZT) and pave the way to use this material as an excellent candidate for thermoelectric materials. We have estimated the thermal conductivity of Sb2Te3 flake with the thickness of 115 nm supported on 300-nm SiO2/Si substrate which is found to be ~ 10 W/m–K. The slightly higher thermal conductivity value suggests that the supporting substrate significantly affects the heat dissipation of the Sb2Te3 flake.

Phase Diagram of the W-doped Pb(Zn1/3Nb2/3)O3–BaTiO3– PbTiO3 System Around a Morphotropic Phase Boundary Composition

2002 ◽  
Vol 17 (5) ◽  
pp. 1085-1091 ◽  
Author(s):  
W. Z. Zhu ◽  
M. Yan ◽  
A. L. Kholkin ◽  
P. Q. Mantas ◽  
J. L. Baptista
Keyword(s):  
High Temperature ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Room Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Electrical Neutrality ◽  
Phase Boundary Composition ◽  
A Site ◽  
Successive Phase

The morphotropic phase boundary (MPB) composition that is characterized by the coexistence of rhombohedral and tetragonal phases in the Pb(Zn1/3Nb2/3)O3–BaTiO3– PbTiO3 system was modified by W-doping at the B site of a perovskite structural block. To maintain the electrical neutrality, creation of A-site vacancies was intentionally introduced in the formulation of the examined compositions. Incorporation of W ions was revealed to stabilize the tetragonal phase against the rhombohedral one, shifting the MPB toward the PZN-rich end at room temperature. High-temperature x-ray diffraction examination in combination with dielectric measurements discloses two successive phase transitions as a sample is cooled from high temperature, namely, paraelectric cubic to ferroelectric rhombohedral followed by ferroelectric rhombohedral to ferroelectric tetragonal. W addition appears to suppress the first transition while promoting the second one.

Raman spectroscopy of Pb(Zr1−xTix)O3graded ceramics around the morphotropic phase boundary

2011 ◽  
Vol 84 (5-6) ◽  
pp. 528-541 ◽  
Author(s):  
E. Buixaderas ◽  
M. Berta ◽  
L. Kozielski ◽  
I. Gregora
Keyword(s):  
Raman Spectroscopy ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary
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