Laser spectroscopic gas concentration measurements in situations with unknown optical path length enabled by absorption line shape analysis

2013 ◽  
Vol 103 (3) ◽  
pp. 034105 ◽  
Author(s):  
P. Lundin ◽  
L. Mei ◽  
S. Andersson-Engels ◽  
S. Svanberg
Keyword(s):  
Absorption Line ◽  
Shape Analysis ◽  
Line Shape ◽  
Path Length ◽  
Optical Path Length ◽  
Optical Path ◽  
Gas Concentration ◽  
Line Shape Analysis ◽  
Laser Spectroscopic ◽  
Absorption Line Shape

Investigation of particulate systems using optical pathlength spectroscopy

2000 ◽  
Vol 627 ◽  
Author(s):  
Gabriel Popescu ◽  
Aristide Dogariu
Keyword(s):  
Path Length ◽  
Random Media ◽  
Michelson Interferometer ◽  
Industrial Process ◽  
Optical Path Length ◽  
Industrial Applications ◽  
Optical Path ◽  
Interference Signal ◽  
Optical Length ◽  
Reference Mirror

ABSTRACTIn many industrial applications involving granular media, knowledge about the structural transformations suffered during the industrial process is desirable. Optical techniques are noninvasive, fast, and versatile tools for monitoring such transformations. We have recently introduced optical path-length spectroscopy as a new technique for random media investigation. The principle of the method is to use a partially coherent source in a Michelson interferometer, where the fields from a reference mirror and the sample are combined to obtain an interference signal. When the system under investigation is a multiple-scattering medium, by tuning the optical length of the reference arm, the optical path-length probability density of light backscattered from the sample is obtained. This distribution carries information about the structural details of the medium. In the present paper, we apply the technique of optical path-length spectroscopy to investigate inhomogeneous distributions of particulate dielectrics such as ceramics and powders. The experiments are performed on suspensions of systems with different solid loads, as well as on powders and suspensions of particles with different sizes. We show that the methodology is highly sensitive to changes in volume concentration and particle size and, therefore, it can be successfully used for real-time monitoring. In addition, the technique is fiber optic-based and has all the advantages associated with the inherent versatility.

Determination of the Accurate Values of the Rate Constant and Thermodynamic Parameters for the Rotation About the C(sp2)-C(aryl) Bond; Adamantan-1-yl 3-Bromo-2,4,6-trimethylphenyl Ketone

1998 ◽  
Vol 63 (7) ◽  
pp. 955-966
Author(s):  
Eva Přibylová ◽  
Miroslav Holík
Keyword(s):  
Thermodynamic Parameters ◽  
Shape Analysis ◽  
Rate Constants ◽  
Line Shape ◽  
Microsoft Excel ◽  
Hindered Rotation ◽  
H Nmr ◽  
Line Shape Analysis ◽  
Coalescence Temperature

Four programs for the 1H NMR line shape analysis: two commercial - Winkubo (Bruker) and DNMR5 (QCPE 165) and two written in our laboratory - Newton (in Microsoft Excel) and Simtex (in Matlab) have been tested in order to get highly accurate rate constants of the hindered rotation about a single bond. For this purpose four testing criteria were used, two of them were also developed by us. As supplementary determinations the rate constants obtained for the coalescence temperature and for the thermal racemization of chromatographically separated enantiomers were used which fitted well the temperature dependence of the rate constants determined by the line shape analysis. As a test compound adamantan-1-yl 3-bromo-2,4,6-trimethylphenyl ketone was prepared and studied. It was shown that supermodified simplex method used in our algorithm (Simtex), though time consuming, gives the most accurate values of the rate constants and consequently the calculated thermodynamic parameters Ea, ∆H≠, and ∆S≠ lay in relatively narrow confidence intervals.

scholarly journals Stray light characterization with ultrafast time-of-flight imaging

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
L. Clermont ◽  
W. Uhring ◽  
M. Georges
Keyword(s):  
Path Length ◽  
Imaging System ◽  
Time Of Flight ◽  
Optical Path Length ◽  
Optical Path ◽  
Stray Light ◽  
Laser Source ◽  
Space Telescopes ◽  
Characterization Methods ◽  
Instance Space

AbstractUnderstanding stray light (SL) is a crucial aspect in the development of high-end optical instruments, for instance space telescopes. As it drives image quality, SL must be controlled by design and characterized experimentally. However, conventional SL characterization methods are limited as they do not provide information on its origins. The problem is complex due to the diversity of light interaction processes with surfaces, creating various SL contributors. Therefore, when SL level is higher than expected, it can be difficult to determine how to improve the system. We demonstrate a new approach, ultrafast time-of-flight SL characterization, where a pulsed laser source and a streak camera are used to record individually SL contributors which travel with a specific optical path length. Furthermore, the optical path length offers a means of identification to determine its origin. We demonstrate this method in an imaging system, measuring and identifying individual ghosts and scattering components. We then show how it can be used to reverse-engineer the instrument SL origins.

Cope rearrangement of 9-methylenebarbaralane. Complete line shape analysis

1973 ◽  
Vol 38 (6) ◽  
pp. 1210-1215 ◽  
Author(s):  
Linda G. Greifenstein ◽  
Joseph B. Lambert ◽  
Michael J. Broadhurst ◽  
Leo A. Paquette
Keyword(s):  
Shape Analysis ◽  
Line Shape ◽  
Cope Rearrangement ◽  
Line Shape Analysis
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