Correlation between charge-transfer complex formation and positional disorder in a binary donor–acceptor glass

2000 ◽  
Vol 112 (16) ◽  
pp. 7190-7194 ◽  
Author(s):  
A. Schreiber ◽  
S. J. Zilker ◽  
D. Haarer
Keyword(s):  
Charge Transfer ◽  
Complex Formation ◽  
Charge Transfer Complex ◽  
Positional Disorder ◽  
Donor Acceptor

Homeotropic alignment through charge-transfer-induced columnar mesophase formation in an unsymmetrically substituted triphenylene derivative

2010 ◽  
Vol 82 (11) ◽  
pp. 1993-2003 ◽  
Author(s):  
Juanjuan Li ◽  
Zhiqun He ◽  
Huan Zhao ◽  
Hemant Gopee ◽  
Xiangfei Kong ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
X Ray Diffraction ◽  
Hexagonal Symmetry ◽  
X Ray ◽  
Mesophase Formation ◽  
Homeotropic Orientation ◽  
Donor Acceptor ◽  
Homeotropic Alignment ◽  
Spectroscopy Optical

An unsymmetrically substituted triphenylene, with two adjacent chloroethoxyethyl lateral flexible chains, was synthesized and characterized. Although this compound showed no mesomorphic behavior, it formed a donor–acceptor charge-transfer complex with 2,4,7-trinitrofluorenone (TNF). The resulting 1:1 complex has been investigated using UV–vis and IR spectroscopy, optical microscopy, thermal analysis, and X-ray diffraction. A columnar mesophase with hexagonal symmetry was found. More interestingly, this charge-transfer complex can be easily aligned on a glass surface in a homeotropic orientation, which is stable at room temperature (RT) and over a wide temperature range.

A new route towards deep desulfurization: selective charge transfer complex formation

1998 ◽  
pp. 305-306 ◽  
Author(s):  
Valérie Meille ◽  
Emmanuelle Schulz ◽  
Valérie Meille ◽  
Michel Vrinat ◽  
Marc Lemaire
Keyword(s):  
Charge Transfer ◽  
Complex Formation ◽  
Charge Transfer Complex ◽  
Deep Desulfurization

scholarly journals DETERMINATION OF TRIMETHOPRIM BY CHARGE-TRANSFER COMPLEX FORMATION

1994 ◽  
Vol 3 (2) ◽  
pp. 132-141
Author(s):  
Mohamed El Balkiny ◽  
Gamal Ragab ◽  
Magda Ayad
Keyword(s):  
Charge Transfer ◽  
Complex Formation ◽  
Charge Transfer Complex

scholarly journals Novel-Type Charge-Transfer Complex Formation between Indoxyl Sulfate and Anthraquinonesulfonate Ions in an Aqueous Polyelectrolyte Solution

2003 ◽  
Vol 35 (1) ◽  
pp. 50-55 ◽  
Author(s):  
Yoshiya Kawabata ◽  
Tomoyuki Itaya ◽  
Kazuyoshi Ueda ◽  
Hiroshi Ochiai ◽  
Yuriko Aoki ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Complex Formation ◽  
Charge Transfer Complex ◽  
Indoxyl Sulfate ◽  
Polyelectrolyte Solution

Ground-state charge-transfer complex formation in hybrid poly(3-hexyl thiophene):titanium dioxide solar cells

2008 ◽  
Vol 93 (22) ◽  
pp. 223302 ◽  
Author(s):  
I. Haeldermans ◽  
K. Vandewal ◽  
W. D. Oosterbaan ◽  
A. Gadisa ◽  
J. D’Haen ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Solar Cells ◽  
Charge Transfer ◽  
Complex Formation ◽  
Ground State ◽  
Charge Transfer Complex ◽  
State Charge
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