Temperature dependence conductivity in organic charge transfer complexes: A theoretical view

Hydride Transfer from 9-Substituted 10-Methyl-9,10-dihydroacridines to Hydride Acceptors via Charge-Transfer Complexes and Sequential Electron−Proton−Electron Transfer. A Negative Temperature Dependence of the Rates

Journal of the American Chemical Society ◽

10.1021/ja9941375 ◽

2000 ◽

Vol 122 (18) ◽

pp. 4286-4294 ◽

Cited By ~ 84

Author(s):

Shunichi Fukuzumi ◽

Kei Ohkubo ◽

Yoshihiro Tokuda ◽

Tomoyoshi Suenobu

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Temperature Dependence ◽

Hydride Transfer ◽

Negative Temperature ◽

Charge Transfer Complexes ◽

Sequential Electron

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Electrical conduction in organic charge transfer complexes under pressure: A theoretical view

10.1063/1.4946745 ◽

2016 ◽

Cited By ~ 1

Author(s):

Yadunath Singh

Keyword(s):

Charge Transfer ◽

Electrical Conduction ◽

Charge Transfer Complexes ◽

Theoretical View

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Electron-Transfer Oxidation of Coenzyme B12Model Compounds and Facile Cleavage of the Cobalt(IV)−Carbon Bond via Charge-Transfer Complexes with Bases. A Negative Temperature Dependence of the Rates

The Journal of Physical Chemistry A ◽

10.1021/jp0453008 ◽

2005 ◽

Vol 109 (6) ◽

pp. 1105-1113 ◽

Cited By ~ 20

Author(s):

Kei Ohkubo ◽

Shunichi Fukuzumi

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Temperature Dependence ◽

Negative Temperature ◽

Charge Transfer Complexes ◽

Carbon Bond

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Magnetic properties of new charge-transfer complexes based on manganese porphyrins

Molecular Physics ◽

10.1080/00268979709482621 ◽

1997 ◽

Vol 90 (3) ◽

pp. 407-413

Author(s):

MARC KELEMEN ◽

CHRISTOPH WACHTER ◽

HUBERT WINTER ◽

ELMAR DORMANN ◽

RUDOLF GOMPPER ◽

...

Keyword(s):

Magnetic Properties ◽

Charge Transfer ◽

Charge Transfer Complexes ◽

Manganese Porphyrins

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MAGNETIC SUSCEPTIBILITES OF CONDUCTIVE CHARGE TRANSFER COMPLEXES

Le Journal de Physique Colloques ◽

10.1051/jphyscol/1983124 ◽

1983 ◽

Vol 44 (C3) ◽

pp. C3-997-C3-1000

Author(s):

J. Tanaka ◽

C. Tanaka

Keyword(s):

Charge Transfer ◽

Charge Transfer Complexes

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Charge Transfer Complexation Boosts Molecular Conductance Through Fermi Level Pinning

10.26434/chemrxiv.7110788 ◽

2018 ◽

Author(s):

Kun Wang ◽

Andrea Vezzoli ◽

Iain Grace ◽

Maeve McLaughlin ◽

Richard Nichols ◽

...

Keyword(s):

Charge Transfer ◽

Single Molecule ◽

Quantum Interference ◽

Transmission Function ◽

Scanning Tunneling ◽

Charge Transfer Complexes ◽

Tunneling Microscopy ◽

Quantum Interference Effect ◽

Single Molecule Junctions ◽

Charge Transfer Complexation

We have used scanning tunneling microscopy to create and study single molecule junctions with thioether-terminated oligothiophene molecules. We find that the conductance of these junctions increases upon formation of charge transfer complexes of the molecules with tetracyanoethene, and that the extent of the conductance increase is greater the longer is the oligothiophene, i.e. the lower is the conductance of the uncomplexed molecule in the junction. We use non-equilibrium Green's function transport calculations to explore the reasons for this theoretically, and find that new resonances appear in the transmission function, pinned close to the Fermi energy of the contacts, as a consequence of the charge transfer interaction. This is an example of a room temperature quantum interference effect, which in this case boosts junction conductance in contrast to earlier observations of QI that result in diminished conductance.<br>

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