Giant enhancement of electron-induced dissociation of chlorofluorocarbons coadsorbed with water or ammonia ices: Implications for atmospheric ozone depletion

1999 ◽  
Vol 111 (7) ◽  
pp. 2861-2864 ◽  
Author(s):  
Q.-B. Lu ◽  
Theodore E. Madey
Keyword(s):  
Ozone Depletion ◽  
Atmospheric Ozone

scholarly journals The role of open lead interactions in atmospheric ozone variability between Arctic coastal and inland sites

Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
Peter K. Peterson ◽  
Kerri A. Pratt ◽  
William R. Simpson ◽  
Son V. Nghiem ◽  
Lemuel X. Pérez Pérez ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Ozone Depletion ◽  
Surface Ozone ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Ozone ◽  
Vertical Profiles ◽  
Large Spatial Scale ◽  
Near Surface ◽  
Air Masses

Abstract Boundary layer atmospheric ozone depletion events (ODEs) are commonly observed across polar sea ice regions following polar sunrise. During March-April 2005 in Alaska, the coastal site of Barrow and inland site of Atqasuk experienced ODEs (O3< 10 nmol mol-1) concurrently for 31% of the observations, consistent with large spatial scale ozone depletion. However, 7% of the time ODEs were exclusively observed inland at Atqasuk. This phenomenon also occurred during one of nine flights during the BRomine, Ozone, and Mercury EXperiment (BROMEX), when atmospheric vertical profiles at both sites showed near-surface ozone depletion only at Atqasuk on 28 March 2012. Concurrent in-flight BrO measurements made using nadir scanning differential optical absorption spectroscopy (DOAS) showed the differences in ozone vertical profiles at these two sites could not be attributed to differences in locally occurring halogen chemistry. During both studies, backward air mass trajectories showed that the Barrow air masses observed had interacted with open sea ice leads, causing increased vertical mixing and recovery of ozone at Barrow and not Atqasuk, where the air masses only interacted with tundra and consolidated sea ice. These observations suggest that, while it is typical for coastal and inland sites to have similar ozone conditions, open leads may cause heterogeneity in the chemical composition of the springtime Arctic boundary layer over coastal and inland areas adjacent to sea ice regions.

scholarly journals COSMIC-RAY-DRIVEN REACTION AND GREENHOUSE EFFECT OF HALOGENATED MOLECULES: CULPRITS FOR ATMOSPHERIC OZONE DEPLETION AND GLOBAL CLIMATE CHANGE

2013 ◽  
Vol 27 (17) ◽  
pp. 1350073 ◽  
Author(s):  
Q.-B. LU
Keyword(s):  
Climate Change ◽  
Surface Temperature ◽  
Global Climate Change ◽  
Greenhouse Effect ◽  
Ozone Depletion ◽  
Global Climate ◽  
Cosmic Ray ◽  
Atmospheric Ozone ◽  
Global Surface Temperature ◽  
Global Surface

This study is focused on the effects of cosmic rays (solar activity) and halogen-containing molecules (mainly chlorofluorocarbons — CFCs) on atmospheric ozone depletion and global climate change. Brief reviews are first given on the cosmic-ray-driven electron-induced-reaction (CRE) theory for O 3 depletion and the warming theory of halogenated molecules for climate change. Then natural and anthropogenic contributions to these phenomena are examined in detail and separated well through in-depth statistical analyses of comprehensive measured datasets of quantities, including cosmic rays (CRs), total solar irradiance, sunspot number, halogenated gases (CFCs, CCl 4 and HCFCs), CO 2, total O 3, lower stratospheric temperatures and global surface temperatures. For O 3 depletion, it is shown that an analytical equation derived from the CRE theory reproduces well 11-year cyclic variations of both polar O 3 loss and stratospheric cooling, and new statistical analyses of the CRE equation with observed data of total O 3 and stratospheric temperature give high linear correlation coefficients ≥ 0.92. After the removal of the CR effect, a pronounced recovery by 20 ~ 25 % of the Antarctic O 3 hole is found, while no recovery of O 3 loss in mid-latitudes has been observed. These results show both the correctness and dominance of the CRE mechanism and the success of the Montreal Protocol. For global climate change, in-depth analyses of the observed data clearly show that the solar effect and human-made halogenated gases played the dominant role in Earth's climate change prior to and after 1970, respectively. Remarkably, a statistical analysis gives a nearly zero correlation coefficient (R = -0.05) between corrected global surface temperature data by removing the solar effect and CO 2 concentration during 1850–1970. In striking contrast, a nearly perfect linear correlation with coefficients as high as 0.96–0.97 is found between corrected or uncorrected global surface temperature and total amount of stratospheric halogenated gases during 1970–2012. Furthermore, a new theoretical calculation on the greenhouse effect of halogenated gases shows that they (mainly CFCs) could alone result in the global surface temperature rise of ~0.6°C in 1970–2002. These results provide solid evidence that recent global warming was indeed caused by the greenhouse effect of anthropogenic halogenated gases. Thus, a slow reversal of global temperature to the 1950 value is predicted for coming 5 ~ 7 decades. It is also expected that the global sea level will continue to rise in coming 1 ~ 2 decades until the effect of the global temperature recovery dominates over that of the polar O 3 hole recovery; after that, both will drop concurrently. All the observed, analytical and theoretical results presented lead to a convincing conclusion that both the CRE mechanism and the CFC-warming mechanism not only provide new fundamental understandings of the O 3 hole and global climate change but have superior predictive capabilities, compared with the conventional models.

A theoretical model of atmospheric ozone depletion

1994 ◽  
Vol 66 (3) ◽  
pp. 279-284 ◽  
Author(s):  
S. K. Midya ◽  
P. K. Jana ◽  
T. Lahiri
Keyword(s):  
Theoretical Model ◽  
Ozone Depletion ◽  
Atmospheric Ozone

scholarly journals A chemistry-transport model simulation of middle atmospheric ozone from 1980 to 2019 using coupled chemistry GCM winds and temperatures

2007 ◽  
Vol 7 (1) ◽  
pp. 1143-1181 ◽  
Author(s):  
J. Damski ◽  
L. Thölix ◽  
L. Backman ◽  
J. Kaurola ◽  
P. Taalas ◽  
...  
Keyword(s):  
Climate Change ◽  
High Latitude ◽  
Ozone Depletion ◽  
Transport Model ◽  
Model Simulation ◽  
Atmospheric Ozone ◽  
High Latitudes ◽  
Future Period ◽  
Chemistry Transport Model ◽  
The Past

Abstract. A Global 40-year simulation from 1980 to 2019 was performed with the FinROSE chemistry-transport model based on the use of coupled chemistry GCM-data. The main focus of our analysis is on climatological-scale processes in high latitudes. The resulting trend estimates for the past period (1980–1999) agree well with observation-based trend estimates. The results for the future period (2000–2019) suggest that the extent of seasonal ozone depletion over both northern and southern high-latitudes has likely reached its maximum. Furthermore, while climate change is expected to cool the stratosphere, this cooling is unlikely to accelerate significantly high latitude ozone depletion. However, the recovery of seasonal high latitude ozone losses will not take place during the next 15 years.

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