Vibrational spectra of molecular ions isolated in solid neon. XV. Infrared spectroscopic evidence for NeHF+ and HFFH+

1999 ◽  
Vol 110 (11) ◽  
pp. 5037-5046 ◽  
Author(s):  
Catherine L. Lugez ◽  
Marilyn E. Jacox ◽  
Russell D. Johnson
Keyword(s):  
Vibrational Spectra ◽  
Molecular Ions ◽  
Spectroscopic Evidence ◽  
Infrared Spectroscopic

Syntheses and vibrational spectra of some tris(alkanethiolato)mercurate(II) complexes, and crystal structure of the Hexakis(methanethiolato)dimercurate(II) dianion

1984 ◽  
Vol 37 (8) ◽  
pp. 1607 ◽  
Author(s):  
GA Bowmaker ◽  
IG Dance ◽  
BC Dobson ◽  
DA Rogers
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Vibrational Spectra ◽  
Crystal Data ◽  
Tetrahedral Geometry ◽  
Space Group ◽  
Spectroscopic Evidence ◽  
Distorted Tetrahedral Geometry ◽  
Complex Anions

The complexes [cation] [Hg(SR)3](R = Me, cation = Et4N+; R = But, cation = Et4N+, Bu4N+, [N(Ph3P)2]+) have been prepared. The crystal structure of the methanethiolate complex shows that it contains centrosymmetric dinuclear anions [(MeS)2Hg(�-SMe)2Hg(SMe)2]2- with distorted tetrahedral geometry about the mercury atoms. Vibrational spectroscopic evidence suggests that this complex dissociates on dissolution in ethanol to give mononuclear [Hg(SMe)3]- species. The ButS- complexes appear to exist as mononuclear [Hg(SBut)3]- species both in the solid state and in solution. The metal-sulfur stretching frequencies are assigned for all of the complexes studied, and the vibrational spectra are discussed in terms of the structures of the complex anions involved. Crystal data for [(C2H5)4N]2Hg2(SCH3)6 : a 8.656(5), b gS130(6), c 12.368(8) �; α 102.16(4), β 105.51(4), γ 105.29(4)�; space group P1, Z 1, R 0.034, Rw 0.042.

Ethylene Hydroformylation with Carbon Dioxide Catalyzed by Ruthenium Supported on Titanate Nanotubes: Infrared Spectroscopic Evidence of Surface Species

2021 ◽  
Vol 6 (40) ◽  
pp. 10758-10766
Author(s):  
Alejandra Chavez‐Mulsa ◽  
Juan C. Fierro‐Gonzalez ◽  
Brent E. Handy ◽  
Iván Alonso Santos‐López ◽  
Sergio Aarón Jimenez‐Lam ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Titanate Nanotubes ◽  
Surface Species ◽  
Spectroscopic Evidence ◽  
Infrared Spectroscopic ◽  
Ethylene Hydroformylation

The vibrational spectra of molecular ions isolated in solid neon. XVI. SO2+, SO2−, and (SO2)2−

2000 ◽  
Vol 113 (1) ◽  
pp. 86-97 ◽  
Author(s):  
Daniel Forney ◽  
C. Brian Kellogg ◽  
Warren E. Thompson ◽  
Marilyn E. Jacox
Keyword(s):  
Vibrational Spectra ◽  
Molecular Ions

The vibrational spectra of molecular ions isolated in solid neon. II. O+4 and O−4

1989 ◽  
Vol 91 (7) ◽  
pp. 3826-3837 ◽  
Author(s):  
Warren E. Thompson ◽  
Marilyn E. Jacox
Keyword(s):  
Vibrational Spectra ◽  
Molecular Ions
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