Three-dimensional nonperturbative analytic model of vibrational energy transfer in atom–molecule collisions

1998 ◽  
Vol 109 (18) ◽  
pp. 7711-7724 ◽  
Author(s):  
Igor V. Adamovich ◽  
J. William Rich
1958 ◽  
Vol 36 (1) ◽  
pp. 96-101 ◽  
Author(s):  
B. Stevens

The effects of intramolecular redistribution of vibrational energy on both the fate of an excited complex molecule and the appearance of its electronic spectra are discussed in terms of a three-dimensional energy surface. It is suggested that continuous absorption be used as a criterion for the application of classical methods to intra- and inter-molecular vibrational energy transfer in those cases where fluorescence emission is observed.


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