scholarly journals Understanding adsorption-induced structural transitions in metal-organic frameworks: From the unit cell to the crystal

2012 ◽  
Vol 137 (18) ◽  
pp. 184702 ◽  
Author(s):  
Carles Triguero ◽  
François-Xavier Coudert ◽  
Anne Boutin ◽  
Alain H. Fuchs ◽  
Alexander V. Neimark
Keyword(s):  
Metal Organic Frameworks ◽  
Unit Cell ◽  
Structural Transitions ◽  
Metal Organic

scholarly journals Adsorption Deformation and Structural Transitions in Metal–Organic Frameworks: From the Unit Cell to the Crystal

2013 ◽  
Vol 4 (19) ◽  
pp. 3198-3205 ◽  
Author(s):  
François-Xavier Coudert ◽  
Anne Boutin ◽  
Alain H. Fuchs ◽  
Alexander V. Neimark
Keyword(s):  
Metal Organic Frameworks ◽  
Unit Cell ◽  
Structural Transitions ◽  
Adsorption Deformation ◽  
Metal Organic

Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66

2016 ◽  
Vol 138 (12) ◽  
pp. 4178-4185 ◽  
Author(s):  
Ana E. Platero-Prats ◽  
Andreas Mavrandonakis ◽  
Leighanne C. Gallington ◽  
Yangyang Liu ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Metal Organic Frameworks ◽  
Structural Transitions ◽  
Local Structures ◽  
Metal Organic

Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2121-2125 ◽  
Author(s):  
Fang Wang ◽  
Hongliang Wang ◽  
Tao Li
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
Random Copolymer ◽  
Unit Cell ◽  
Random Copolymers ◽  
Unit Cell Parameters ◽  
Cell Parameters ◽  
Metal Organic ◽  
Distinct Unit

A series of random copolymers are used as molecular glues to bridge the interfaces between metal–organic frameworks with distinct unit cell parameters and coordination chemistry.

scholarly journals Exact matrix treatment of an osmotic ensemble model of adsorption and pressure induced structural transitions in metal organic frameworks

2016 ◽  
Vol 45 (10) ◽  
pp. 4213-4217 ◽  
Author(s):  
Lawrence J. Dunne ◽  
George Manos
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Transformations ◽  
Ensemble Model ◽  
Structural Transitions ◽  
One Dimensional ◽  
Metal Organic ◽  
Statistical Mechanical ◽  
Exact Matrix

Here we present an exactly treated quasi-one dimensional statistical mechanical osmotic ensemble model of pressure and adsorption induced breathing structural transformations of metal–organic frameworks (MOFs).

scholarly journals Metal–organic frameworks: the pressure is on

2015 ◽  
Vol 71 (6) ◽  
pp. 585-586 ◽  
Author(s):  
François-Xavier Coudert
Keyword(s):  
Mechanical Properties ◽  
Mechanical Stability ◽  
Metal Organic Frameworks ◽  
Structural Transitions ◽  
Framework Materials ◽  
Metal Organic ◽  
Industrial Level ◽  
High Mechanical Stability ◽  
Linear Compressibility

Metal–organic frameworks (MOFs) demonstrate a wide variety of behavior in their response to pressure, including anomalous mechanical properties, negative linear compressibility, pressure-induced crystal-to-crystal and crystal-to-amorphous structural transitions. The discovery of framework materials combining novel pressure responses and high mechanical stability is key in the quest for applications of MOFs at the industrial level.

scholarly journals A Cationic Thorium-Organic Framework with Triple Single-Crystal-to-Single-Crystal Transformation Peculiarities for Ultrasensitive Anion Recognition

2021 ◽  
Author(s):  
Zi-Jian Li ◽  
Min Lei ◽  
Hong-liang Bao ◽  
Ju Yu ◽  
Huangjie Lu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Anion Recognition ◽  
Direct Visualization ◽  
Structural Transitions ◽  
New Materials ◽  
Crystal Transformation ◽  
Metal Organic ◽  
The Creation ◽  
Organic Framework

Single-crystal-to-single-crystal transformation of metal-organic frameworks has been met with great interest, as it allows for the creation of new materials in stepwise manners and direct visualization of structural transitions when...

Discovery of hypothetical hetero-interpenetrated MOFs with arbitrarily dissimilar topologies and unit cell shapes

CrystEngComm ◽  
2017 ◽  
Vol 19 (31) ◽  
pp. 4497-4504 ◽  
Author(s):  
K. B. Sezginel ◽  
T. Feng ◽  
C. E. Wilmer
Keyword(s):  
Metal Organic Frameworks ◽  
Unit Cell ◽  
Cell Shapes ◽  
Metal Organic ◽  
Novel Algorithm

Interpenetration is a commonly observed phenomenon in metal organic frameworks (MOFs) where multiple frameworks are entangled with each other. Using a novel algorithm described here, 18 hypothetical hetero-interpenetrated MOFs were discovered.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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