Time-averaging approximation in the interaction picture: Anisotropy of vibrational pump-probe experiments for coupled chromophores with application to liquid water

2012 ◽  
Vol 137 (15) ◽  
pp. 154102
Author(s):  
Mino Yang
Keyword(s):  
Liquid Water ◽  
Time Averaging ◽  
Interaction Picture ◽  
Pump Probe

Terahertz pump-probe of liquid water at 12.3 THz

2021 ◽  
Author(s):  
Fabio Novelli ◽  
Claudius Hoberg ◽  
Ellen M. Adams ◽  
J. Michael Klopf ◽  
Martina Havenith
Keyword(s):  
Liquid Water ◽  
Nonlinear Response ◽  
Thz Spectroscopy ◽  
Water Network ◽  
Pump Probe ◽  
Dynamical Complexity ◽  
Hydrogen Bonded

The dynamical complexity of the hydrogen-bonded water network can be investigated with intense Terahertz (THz) spectroscopy, which can drive the liquid into the nonlinear response regime and probe anharmonicity effects....

scholarly journals Libration induced stretching mode excitation for pump-probe spectroscopy in pure liquid water

2004 ◽  
Vol 121 (16) ◽  
pp. 7908 ◽  
Author(s):  
Wafa Amir ◽  
Guilhem Gallot ◽  
François Hache
Keyword(s):  
Liquid Water ◽  
Pure Liquid ◽  
Pump Probe ◽  
Mode Excitation ◽  
Probe Spectroscopy

Conformation of the neurotransmitter γ-aminobutyric acid in liquid water

2014 ◽  
Vol 16 (22) ◽  
pp. 10433-10437 ◽  
Author(s):  
N. Ottosson ◽  
M. Pastorczak ◽  
Sietse T. van der Post ◽  
Huib J. Bakker
Keyword(s):  
Spectroscopic Study ◽  
Liquid Water ◽  
Aminobutyric Acid ◽  
Pump Probe

A combined dielectric and mid-IR pump–probe spectroscopic study reveals zwitterionic GABA to exist in predominately extended conformations in liquid water.

On the Consequences of Resampling Microwave Radiometer Observations for Use in Retrieval Algorithms

2009 ◽  
Vol 48 (9) ◽  
pp. 1981-1993 ◽  
Author(s):  
Anita D. Rapp ◽  
M. Lebsock ◽  
C. Kummerow
Keyword(s):  
Wind Speed ◽  
Liquid Water ◽  
Microwave Radiometer ◽  
Retrieval Algorithm ◽  
Time Averaging ◽  
Liquid Water Path ◽  
Cloud Liquid Water ◽  
Water Path ◽  
Brightness Temperatures ◽  
Cloud Liquid Water Path

Abstract How to deal with the different spatial resolutions of multifrequency satellite microwave radiometer measurements is a common problem in retrievals of cloud properties and rainfall. Data convolution and deconvolution is a common approach to resampling the measurements to a single resolution. Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) measurements are resampled to the resolution of the 19-GHz field of view for use in a multifrequency optimal estimation retrieval algorithm of cloud liquid water path, total precipitable water, and wind speed. Resampling the TMI measurements is found to have a strong influence on retrievals of cloud liquid water path and a slight influence on wind speed. Beam-filling effects in the resampled brightness temperatures are shown to be responsible for the large differences between the retrievals using the TMI native resolution and resampled brightness temperatures. Synthetic retrievals are performed to test the sensitivity of the retrieved parameters to beam-filling effects in the resampling of each of the different channels. Beam-filling effects due to the convolution of the 85-GHz channels are shown to be the largest contributor to differences in retrieved cloud liquid water path. Differences in retrieved wind speeds are found to be a combination of effects from deconvolving the 10-GHz brightness temperatures and compensation effects due to the lower liquid water path being retrieved by the high-frequency channels. The influence of beam-filling effects on daily and monthly averages of cloud liquid water path is also explored. Results show that space–time averaging of cloud liquid water path cannot fully compensate for the beam-filling effects and should be considered when using cloud liquid water path data for validation or in climate studies.

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