Computational determination of theÃstate absorption spectrum of NH3and of ND3using a new quasi-diabatic representation of the X̃ andÃstates and full six-dimensional quantum dynamics

2012 ◽  
Vol 136 (23) ◽  
pp. 234301 ◽  
Author(s):  
Xiaolei Zhu ◽  
JianYi Ma ◽  
David R. Yarkony ◽  
Hua Guo
Keyword(s):  
Absorption Spectrum ◽  
Quantum Dynamics ◽  
Diabatic Representation

Quantum Resonances: Line Profiles and Dynamics

2003 ◽  
Vol 68 (3) ◽  
pp. 529-553 ◽  
Author(s):  
Ivana Paidarová ◽  
Philippe Durand
Keyword(s):  
Hydrogen Atom ◽  
Operator Theory ◽  
Quantum Dynamics ◽  
Line Profiles ◽  
Static Electric Field ◽  
Reversal Effect ◽  
Quantum Resonances ◽  
Energy Dependent ◽  
Effective Hamiltonians

The wave operator theory of quantum dynamics is reviewed and applied to the study of line profiles and to the determination of the dynamics of interacting resonances. Energy-dependent and energy-independent effective Hamiltonians are investigated. The q-reversal effect in spectroscopy is interpreted in terms of interfering Fano profiles. The dynamics of an hydrogen atom subjected to a strong static electric field is revisited.

scholarly journals Simultaneous Determination of Amlodipine and Valsartan

2011 ◽  
Vol 6 ◽  
pp. ACI.S7282 ◽  
Author(s):  
Nashwah Gadallah Mohamed
Keyword(s):  
Absorption Spectrum ◽  
Simultaneous Determination ◽  
Zero Order ◽  
Uv Spectrophotometry ◽  
Ratio Spectrum ◽  
First Derivative ◽  
Bulk Powder ◽  
Overlapped Peaks ◽  
Third Derivative

A spectrophotometric method was developed for simultaneous determination of amlodipine (Aml) and valsartan (Val) without previous separation. In this method amlodipine in methanolic solution was determined using zero order UV spectrophotometry by measuring its absorbency at 360.5 nm without any interference from valsartan. Valsartan spectrum in zero order is totally overlapped with that of amlodipine. First, second and third derivative could not resolve the overlapped peaks. The first derivative of the ratio spectra technique was applied for the measurement of valsartan. The ratio spectrum was obtained by dividing the absorption spectrum of the mixture by that of amlodipine, so that the concentration of valsartan could be determined from the first derivative of the ratio spectrum at 290 nm. Quantification limits of amlodipine and valsartan were 10-80 μg/ml and 20-180 μg/ml respectively. The method was successfully applied for the quantitative determination of both drugs in bulk powder and pharmaceutical formulation.

scholarly journals Measurements of The Spectroscopic Properties of Hydrogen Iodide Molecules

2008 ◽  
Vol 5 (3) ◽  
pp. 446-448
Author(s):  
Baghdad Science Journal
Keyword(s):  
Absorption Spectrum ◽  
Quantum Number ◽  
Rotational Quantum Number ◽  
Spectroscopic Properties ◽  
Hydrogen Iodide

A calculation have been carried out for determination some of the spectroscopic properties of Hydrogen Iodide HI molecules such as, the intensity of the absorption spectrum as a function of the variation of the temperature ranging from 10 to 1000 K. This study shows that the populations and hence intensity of the molecule increased as the temperature increased. Another determination of the maximum rotational quantum number Jmax of N2 , CO , BrF AgCl and HI molecules has been carried out.

STUDIES ON THE DETERMINATION OF PENTOSANS BY ULTRA-VIOLET ABSORPTION SPECTRUM

1958 ◽  
Vol 14 (12) ◽  
pp. 914-919
Author(s):  
Masamichi Okubo ◽  
Koji Nakajima ◽  
Takuji Yoshiwara
Keyword(s):  
Absorption Spectrum ◽  
Ultra Violet

scholarly journals Diffuse Interstellar Bands – The Unidentified Part of the Interstellar Absorption Spectrum

1989 ◽  
Vol 135 ◽  
pp. 67-86 ◽  
Author(s):  
Jacek Krełowski
Keyword(s):  
Absorption Spectrum ◽  
Line Of Sight ◽  
Optical Parameters ◽  
Interstellar Matter ◽  
Molecular Absorption ◽  
Interstellar Clouds ◽  
Diffuse Interstellar Bands ◽  
Intensity Ratios ◽  
Molecular Abundances

The unidentified (since 1921) diffuse interstellar bands (DIBs) are discussed together with their relations to other interstellar absorptions sucn as: continuous extinction, polarization and atomic or molecular absorption lines. It is shown that DIBs do not form the absorption spectrum of one agent, but probably of several (3 or more). DIBs as well as other interstellar absorptions are usually formed in several clouds along a line-of-sight. Thus, they suffer Doppler splitting; the first high resolution profiles free of the latter effect are described. Since single interstellar clouds may differ not only in radial velocities but also in many physical (optical) parameters, the observed interstellar absorptions are ill-defined averages over all clouds situated along any line-of-sight. It is of basic importance to determine not only the single cloud profiles of diffuse bands, but also their relations to other interstellar absorptions in the same clouds. Intensity ratios of DIBs are shown to be sensitive to the shapes of extinction curves, depletion patterns of elements and molecular abundances in the considered clouds. The sensitivity of the DIBs to the variation in polarization is less documented but probably also present. Thus the diffuse lines are presented as the unidentified part of the absorption spectrum of interstellar matter. Their identification depends on the determination of their relations to other interstellar absorptions which must be determined precisely.

Electroretinographic Determination of Spectral Sensitivity in Albino and Pigmented Brook Trout (Salvelinus fontinalis, Mitchill)

1971 ◽  
Vol 49 (12) ◽  
pp. 1030-1037 ◽  
Author(s):  
H. Kobayashi ◽  
M. A. Ali
Keyword(s):  
Absorption Spectrum ◽  
Spectral Sensitivity ◽  
Brook Trout ◽  
Salvelinus Fontinalis ◽  
Narrow Band ◽  
Visible Spectrum ◽  
The Difference

A technique for recording electroretinograms from the unpunctured eyes in situ of living, anesthetized fish is described. This technique permits the use of the same fish in a number of experiments over a period of weeks, months, or years. Using this technique the spectral sensitivity of dark-adapted (scotopic) and light-adapted (photopic) fish was measured at 13 bands of the visible spectrum. The scotopic curves of albino and pigmented trout thus obtained in the winter have their maxima around 525 nm which differ from that of the absorption spectrum of the scotopic pigment in situ and in vitro of older fish obtained in the summer. The photopic curve of the pigmented fish is a broad one with humps around 425 nm, 545 nm, and 595 nm. The albino's curve has a relatively narrow band with a peak around 630 nm and a shoulder at about 550 nm. The difference between the shapes of the two curves may be ascribed to the increase in the intensity of light of longer wavelengths within the eyeball of the albino, due to reflection from blood vessels and sclera caused by the absence of pigmentation.

The absorption spectrum of Cl2 in the vacuum ultraviolet

1981 ◽  
Vol 59 (6) ◽  
pp. 835-840 ◽  
Author(s):  
A. E. Douglas
Keyword(s):  
Absorption Spectrum ◽  
Vacuum Ultraviolet ◽  
Band System ◽  
Rydberg States ◽  
Ultraviolet Region ◽  
Isotopic Molecule ◽  
Vacuum Ultraviolet Region ◽  
Vibrational Constants ◽  
Made In

The absorption spectrum of Cl2 in the vacuum ultraviolet region has been photographed with sufficient resolution to allow rotational analyses of many bands. The separated isotopic molecule 35Cl2 and cooled absorption cells were used to simplify the spectrum. A band system associated with an ionic state has been observed in the 1330–1450 Å range. Many large perturbations in the system prevent the determination of the usual rotational and vibrational constants. Some progress has been made in the analyses of a few bands associated with Rydberg states.

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