Theory of gas–gas phase transition in rare‐gas binary mixtures

1996 ◽  
Vol 105 (5) ◽  
pp. 2020-2027 ◽  
Author(s):  
Lidia Strigari ◽  
Mauro Rovere ◽  
Bruno D’Aguanno
Keyword(s):  
Phase Transition ◽  
Gas Phase ◽  
Binary Mixtures ◽  
Rare Gas

Numerical Analysis of Two-Phase Pipe Flow of Liquid Helium Using Multi-Fluid Model

2001 ◽  
Vol 123 (4) ◽  
pp. 811-818 ◽  
Author(s):  
Jun Ishimoto ◽  
Mamoru Oike ◽  
Kenjiro Kamijo
Keyword(s):  
Phase Transition ◽  
Gas Phase ◽  
Liquid Helium ◽  
Two Phase Flow ◽  
Fluid Model ◽  
Numerical Results ◽  
Phase Flow ◽  
Two Dimensional ◽  
Two Phase ◽  
Normal Fluid

The two-dimensional characteristics of the vapor-liquid two-phase flow of liquid helium in a pipe are numerically investigated to realize the further development and high performance of new cryogenic engineering applications. First, the governing equations of the two-phase flow of liquid helium based on the unsteady thermal nonequilibrium multi-fluid model are presented and several flow characteristics are numerically calculated, taking into account the effect of superfluidity. Based on the numerical results, the two-dimensional structure of the two-phase flow of liquid helium is shown in detail, and it is also found that the phase transition of the normal fluid to the superfluid and the generation of superfluid counterflow against normal fluid flow are conspicuous in the large gas phase volume fraction region where the liquid to gas phase change actively occurs. Furthermore, it is clarified that the mechanism of the He I to He II phase transition caused by the temperature decrease is due to the deprivation of latent heat for vaporization from the liquid phase. According to these theoretical results, the fundamental characteristics of the cryogenic two-phase flow are predicted. The numerical results obtained should contribute to the realization of advanced cryogenic industrial applications.

scholarly journals The Influence of the Nature of Redox-Active Moieties on the Properties of Redox-Active Ionic Liquids and on Their Use as Electrolyte for Supercapacitors

Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6344
Author(s):  
Philipp S. Borchers ◽  
Patrick Gerlach ◽  
Yihan Liu ◽  
Martin D. Hager ◽  
Andrea Balducci ◽  
...  
Keyword(s):  
Phase Transition ◽  
Differential Scanning Calorimetry ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Binary Mixtures ◽  
Thermal Characteristics ◽  
The Other ◽  
Scanning Calorimetry ◽  
Imidazolium Ionic Liquids ◽  
Redox Active

In this work, two new redox-active ionic liquids, one based on 2,2,6,6-tetramethylpiperidine-N-oxide and the other based on 4,4′-bipyridine, are synthesized and characterized. A ferrocene-based redox-active ionic liquid is used for referencing the results. All ionic liquids are formed via salt-metathesis from halogenate to bis(trifluoromethylsulfonyl)imide. Their fundamental thermal characteristics are assessed with differential scanning calorimetry. While the imidazolium ionic liquids show no melting point, the phase transition is well observable for the viologen-based ionic liquid. The properties of the neat redox-active ionic liquids and of binary mixtures containing these ionic liquids (0.1 m) and 1-butyl-1-methyl pyrrolidinium-bis(trifluoromethylsulfonyl)imide have been investigated. Finally, the use of these binary mixtures in combination with activated carbon-based electrodes has been considered in view of the use of these redox-active electrolytes in supercapacitors.

Photodecomposition of gas-phase transition metal carbonyl anions

1974 ◽  
Vol 96 (12) ◽  
pp. 3816-3820 ◽  
Author(s):  
Robert C. Dunbar ◽  
Bennett B. Hutchinson
Keyword(s):  
Phase Transition ◽  
Transition Metal ◽  
Gas Phase ◽  
Metal Carbonyl

scholarly journals Kerr-AdS analogue of triple point and solid/liquid/gas phase transition

2014 ◽  
Vol 31 (4) ◽  
pp. 042001 ◽  
Author(s):  
Natacha Altamirano ◽  
David Kubizňák ◽  
Robert B Mann ◽  
Zeinab Sherkatghanad
Keyword(s):  
Phase Transition ◽  
Gas Phase ◽  
Triple Point ◽  
Solid Liquid
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