Fitting and scaling laws for high temperature Q branch collapse in the O2 stimulated Raman spectra in O2–H2O mixtures

1996 ◽  
Vol 104 (13) ◽  
pp. 5347-5348 ◽  
Author(s):  
G. Millot ◽  
G. Fanjoux ◽  
B. Lavorel
1981 ◽  
Vol 35 (6) ◽  
pp. 582-584 ◽  
Author(s):  
David A. Stephenson

The Raman spectra of CO2 and H2O have been measured from 1000 to 2200°K. The spectra are found to be well described by the simple models described previously. In particular, the simple partition functions of T−1 for CO2 and T−3/2 for H2O are adequate for describing the spectra over the temperature range of interest.


2007 ◽  
Vol 56 (2) ◽  
pp. 1152
Author(s):  
Zhang Xia ◽  
Wan Song-Ming ◽  
Zhang Qing-Li ◽  
Yin Shao-Tang ◽  
You Jing-Lin ◽  
...  

2009 ◽  
Vol 58 (1) ◽  
pp. 570
Author(s):  
Zhou Wen-Ping ◽  
Wan Song-Ming ◽  
Yin Shao-Tang ◽  
Zhang Qing-Li ◽  
You Jing-Lin ◽  
...  

1966 ◽  
Vol 5 (3) ◽  
pp. 473_1 ◽  
Author(s):  
R. V. Wick ◽  
T. A. Wiggins ◽  
D. H. Rank

2020 ◽  
Vol 124 (7) ◽  
pp. 1253-1265
Author(s):  
Martin Pižl ◽  
Alessandra Picchiotti ◽  
Mateusz Rebarz ◽  
Nils Lenngren ◽  
Liu Yingliang ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5453
Author(s):  
Min Wang ◽  
Changhao Wang ◽  
Jian Wang ◽  
Liming Lu ◽  
Xiaoye Gong ◽  
...  

In situ high-temperature Raman spectra of polycrystalline KBi(MoO4)2 were recorded from room temperature to 1073 K. Thermal stability of the monoclinic KBi(MoO4)2 was examined by temperature-dependent XRD. The monoclinic phase transformed into the scheelite tetragonal structure at 833 K, and then to the monoclinic phase at 773 K. Quantum chemistry ab initio calculation was performed to simulate the Raman spectra of the structure of KBi(MoO4)2 high-temperature melt. The experimental Raman band at 1023 K was deconvoluted into seven Gaussian peaks, and the calculated results were in good agreement with the experimental data. Therefore, the vibrational modes of Raman peaks of molten KBi(MoO4)2 were assigned. It was confirmed that the isolated structure of [Bi(MoO4)2]− monomer, consisting of Mo6+ centers and Bi3+ sub-centers connected by edge-sharing, mainly exists in the melt of KBi(MoO4)2.


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