Local structure around Fe ions on multiferroic Pb(Fe1/2Nb1/2)O3 ceramics probed by x-ray absorption spectroscopy

2012 ◽  
Vol 100 (17) ◽  
pp. 172907 ◽  
Author(s):  
A. Mesquita ◽  
B. M. Fraygola ◽  
V. R. Mastelaro ◽  
J. A. Eiras
2019 ◽  
Author(s):  
Jisue Moon ◽  
Carter Abney ◽  
Dmitriy Dolzhnikov ◽  
James M. Kurley ◽  
Kevin A. Beyer ◽  
...  

The local structure of dilute CrCl<sub>3</sub> in a molten MgCl<sub>2</sub>:KCl salt was investigated by <i>in situ</i> x-ray absorption spectroscopy (XAS) at temperatures from room temperature to 800<sup>o</sup>C. This constitutes the first experiment where dilute Cr speciation is explored in a molten chloride salt, ostensibly due to the compounding challenges arising from a low Cr concentration in a matrix of heavy absorbers at extreme temperatures. CrCl<sub>3</sub> was confirmed to be the stable species between 200 and 500<sup>o</sup>C, while mobility of metal ions at higher temperature (>700<sup>o</sup>C) prevented confirmation of the local structure.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4061
Author(s):  
Yongtao Li ◽  
Liqing Liu ◽  
Dehao Wang ◽  
Hongguang Zhang ◽  
Xuemin He ◽  
...  

BiFeO3 is considered as a single phase multiferroic. However, its magnetism is very weak. We study the magnetic properties of BiFeO3 by Cu and (Cu, Zn). Polycrystalline samples Bi(Fe0.95Cu0.05)O3 and BiFe0.95(Zn0.025Cu0.025)O3 are prepared by the sol-gel method. The magnetic properties of BiFe0.95(Zn0.025Cu0.025)O3 are greater than that of BiFeO3 and Bi(Fe0.95Cu0.05)O3. The analyses of X-ray absorption fine structure data show that the doped Cu atoms well occupy the sites of the Fe atoms. X-ray absorption near edge spectra data confirm that the valence state of Fe ions does not change. Cu and Zn metal ion co-doping has no impact on the local structure of the Fe and Bi atoms. The modification of magnetism by doping Zn can be understood by the view of the occupation site of non-magnetically active Zn2+.


2004 ◽  
Vol 108 (42) ◽  
pp. 16372-16376 ◽  
Author(s):  
Aline Léon ◽  
Oliver Kircher ◽  
Jörg Rothe ◽  
Maximilian Fichtner

2013 ◽  
Vol 204 ◽  
pp. 257-265 ◽  
Author(s):  
Natkrita Prasoetsopha ◽  
Supree Pinitsoontorn ◽  
Atipong Bootchanont ◽  
Pinit Kidkhunthod ◽  
Pornjuk Srepusharawoot ◽  
...  

1991 ◽  
Vol 44 (13) ◽  
pp. 6961-6972 ◽  
Author(s):  
J. B. Boyce ◽  
F. G. Bridges ◽  
T. Claeson ◽  
T. H. Geballe ◽  
G. G. Li ◽  
...  

2021 ◽  
pp. 126223
Author(s):  
H. Arima-Osonoi ◽  
K. Yamazaki ◽  
R. Simura ◽  
T. Sugawara ◽  
K. Yubuta ◽  
...  

2002 ◽  
Vol 49 (5) ◽  
pp. 841-850 ◽  
Author(s):  
C. H. Shen ◽  
R. S. Liu ◽  
L.-Y. Jang ◽  
J. F. Lee ◽  
J. M. Chen

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