The dynamics of Rydberg states of molecules in the intermediate regime: The role of the vibrations

1996 ◽  
Vol 104 (5) ◽  
pp. 1937-1952 ◽  
Author(s):  
Eran Rabani ◽  
R. D. Levine
Keyword(s):  
Rydberg States ◽  
Intermediate Regime

The role of high Rydberg states in enhanced O-formation in a pulsed O2discharge

1999 ◽  
Vol 8 (3) ◽  
pp. 384-391 ◽  
Author(s):  
W X Ding ◽  
L A Pinnaduwage ◽  
C Tav ◽  
D L McCorkle
Keyword(s):  
Rydberg States

scholarly journals Role of Rydberg States in the Photochemical Dynamics of Ethylene

2012 ◽  
Vol 116 (11) ◽  
pp. 2808-2818 ◽  
Author(s):  
Toshifumi Mori ◽  
William J. Glover ◽  
Michael S. Schuurman ◽  
Todd J. Martinez
Keyword(s):  
Rydberg States

Evidence of circular Rydberg states in beam-foil experiments: Role of the surface wake field

2017 ◽  
Vol 120 (6) ◽  
pp. 63002 ◽  
Author(s):  
Gaurav Sharma ◽  
Nitin K. Puri ◽  
Pravin Kumar ◽  
T. Nandi
Keyword(s):  
Rydberg States ◽  
Wake Field ◽  
Beam Foil

scholarly journals Time-resolved high harmonic spectroscopy of dynamical symmetry breaking in bi-circular laser fields: the role of Rydberg states

2017 ◽  
Vol 25 (19) ◽  
pp. 22880 ◽  
Author(s):  
Álvaro Jiménez-Galán ◽  
Nickolai Zhavoronkov ◽  
Marcel Schloz ◽  
Felipe Morales ◽  
Misha Ivanov
Keyword(s):  
Symmetry Breaking ◽  
High Harmonic ◽  
Rydberg States ◽  
Dynamical Symmetry ◽  
Laser Fields ◽  
Time Resolved ◽  
Dynamical Symmetry Breaking

The 4s ← 1b1 and 3d ← 1b1 Rydberg states of H2O and D2O: Spectroscopy and predissociation dynamics

1984 ◽  
Vol 62 (12) ◽  
pp. 1806-1833 ◽  
Author(s):  
Michael N. R. Ashfold ◽  
J. Mark Bayley ◽  
Richard N. Dixon
Keyword(s):  
Potential Energy Surfaces ◽  
Vacuum Ultraviolet ◽  
Transition Probabilities ◽  
Line Strength ◽  
Rydberg States ◽  
Photon Ionization ◽  
The One ◽  
Energy Surfaces ◽  
Equilibrium Geometries

Two new electronic states of H2O and D2O have been identified in the energy range 84 000–88 000 cm−1 as three-photon resonances in four-photon ionization spectroscopy. Simulations of the rotational intensity distributions using asymmetric top three-photon line strength theory, and rotational analyses, characterize the states as B1 and A2. These Rydberg states are assigned to the excitations 4sa1 ← 1b1[Formula: see text] and 3d2 ← 1b1[Formula: see text] on the basis of equilibrium geometries, quantum defects, and the polarization dependence of their three-photon transition probabilities. The identification of the one-photon forbidden 1A2–1A1 transition, together with published vacuum ultraviolet (VUV) absorption spectra, permits a consistent assignment for all five members of the 3d ← 1b1 complex.The [Formula: see text] and [Formula: see text] states arc predissociatcd via both homogeneous and heterogeneous mechanisms. The homogeneous channel from the [Formula: see text] state shows a dramatic isotope effect, being about two orders of magnitude faster in H2O than from equivalent levels of D2O. The heterogeneous predissociation exhibits irregular vibronic and isotopic dependencies, which can be rationalized in terms of the intercessional role of accidental near resonances with levels of the heavily predissociated [Formula: see text] state. The (000) levels of the [Formula: see text] states of H2O and D2O show contrasting heterogeneous predissociation behaviour, which can be interpreted with a knowledge of the relevant potential energy surfaces and the electronic–rotational Coriolis interactions that couple the states.

scholarly journals Rotationally resolved photoelectron spectroscopy of the2Σ−Rydberg states of OH: The role of Cooper minima

1991 ◽  
Vol 95 (1) ◽  
pp. 714-716 ◽  
Author(s):  
E. de Beer ◽  
C. A. de Lange ◽  
J. A. Stephens ◽  
Kwanghsi Wang ◽  
V. McKoy
Keyword(s):  
Photoelectron Spectroscopy ◽  
Rydberg States
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