Reaction of atomic oxygen with adsorbed carbon monoxide on a platinum surface

1996 ◽  
Vol 104 (2) ◽  
pp. 742-757 ◽  
Author(s):  
J. Ree ◽  
Y. H. Kim ◽  
H. K. Shin
Keyword(s):  
Carbon Monoxide ◽  
Atomic Oxygen ◽  
Platinum Surface ◽  
Adsorbed Carbon

Low-Fluence Laser Induced Fragmentation and Desorption of 3,4,9,10-Perylenetetracarboxylic Dianhydride (PTCDA) Thin Film

2013 ◽  
Vol 543 ◽  
pp. 30-34 ◽  
Author(s):  
Aljona Ramonova ◽  
Tengiz Butkhuzi ◽  
Viktorija Abaeva ◽  
I.V. Tvauri ◽  
Soslan Khubezhov ◽  
...  
Keyword(s):  
Thin Film ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Kinetic Energy ◽  
Atomic Oxygen ◽  
Laser Light ◽  
Pulsed Laser ◽  
Molecular Fragmentation ◽  
Irradiation Pulse ◽  
Main Effect

Laser-induced fragmentation and desorption of fragments of PTCDA films vacuum-deposited on GaAs (100) substrate has been studied by time-of-flight (TOF) mass spectroscopy. The main effect caused by pulsed laser light irradiation (pulse duration: 10 ns, photon energy: 2.34 eV and laser fluence ranging from 0.5 to 7 mJ/cm2) is PTCDA molecular fragmentation and desorption of the fragments formed, whereas no desorption of intact PTCDA molecule was detected. Fragments formed are perylene core C20H8, its half C10H4, carbon dioxide, carbon monoxide and atomic oxygen. All desorbing fragments have essentially different kinetic energy. The mechanism of photoinduced molecular fragmentation and desorption is discussed.

The oxidation of Carbon with Atomic Oxygen

1959 ◽  
Vol 12 (2) ◽  
pp. 114 ◽  
Author(s):  
JD Blackwood ◽  
FK McTaggart
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Radio Frequency ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Graphitic Carbon ◽  
Carbon Surface ◽  
Direct Oxidation ◽  
Radio Frequency Field ◽  
Frequency Field

Atomic oxygen, produced by dissociation of molecular oxygen in a radio frequency field, will react with amorphous or graphitic carbon at room temperatures and both carbon monoxide and carbon dioxide appear in the product gases. Carbon monoxide appears to be the primary product of oxidation of carbon, the carbon dioxide being produced by direct combination of carbon monoxide with oxygen which takes place mainly at the carbon surface. Atomic oxygen will also react with carbon dioxide to produce carbon monoxide and molecular oxygen but the quantity of carbon monoxide produced by this reaction is small compared to that produced by direct oxidation of the carbon.

The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst

2011 ◽  
Vol 4 (3) ◽  
pp. 177-182 ◽  
Author(s):  
Paramaconi Rodriguez ◽  
Youngkook Kwon ◽  
Marc T. M. Koper
Keyword(s):  
Carbon Monoxide ◽  
Gold Catalyst ◽  
Promoting Effect ◽  
Oxidation Of Alcohols ◽  
Adsorbed Carbon
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