Femtosecond solvation dynamics determining the band shape of stimulated emission from a polar styryl dye

1995 ◽  
Vol 102 (7) ◽  
pp. 2691-2700 ◽  
Author(s):  
Dieter Bingemann ◽  
Nikolaus P. Ernsting
Keyword(s):  
Stimulated Emission ◽  
Solvation Dynamics ◽  
Band Shape ◽  
Styryl Dye

scholarly journals Ratiometric Detection of Mercury (II) Ions in Living Cells Using Fluorescent Probe Based on Bis(styryl) Dye and Azadithia-15-Crown-5 Ether Receptor

Sensors ◽  
2021 ◽  
Vol 21 (2) ◽  
pp. 470
Author(s):  
Pavel A. Panchenko ◽  
Anastasija V. Efremenko ◽  
Alexey V. Feofanov ◽  
Mariya A. Ustimova ◽  
Yuri V. Fedorov ◽  
...  
Keyword(s):  
Intramolecular Charge Transfer ◽  
Resonance Energy Transfer ◽  
Resonance Energy ◽  
Living Cells ◽  
Fluorescence Intensity Ratio ◽  
Imaging Studies ◽  
Band Shape ◽  
Styryl Dye ◽  
Ratiometric Detection ◽  
Bio Imaging

Bis(styryl) dye 1 bearing N-phenylazadithia-15-crown-5 ether receptor has been evaluated as a ratiometric fluorescent chemosensor for mercury (II) ions in living cells. In aqueous solution, probe 1 selectively responds to the presence of Hg2+ via the changes in the emission intensity as well as in the emission band shape, which is a result of formation of the complex with 1:1 metal to ligand ratio (dissociation constant 0.56 ± 0.15 µM). The sensing mechanism is based on the interplay between the RET (resonance energy transfer) and ICT (intramolecular charge transfer) interactions occurring upon the UV/Vis (380 or 405 nm) photoexcitation of both styryl chromophores in probe 1. Bio-imaging studies revealed that the yellow (500–600 nm) to red (600–730 nm) fluorescence intensity ratio decreased from 4.4 ± 0.2 to 1.43 ± 0.10 when cells were exposed to increasing concentration of mercury (II) ions enabling ratiometric quantification of intracellular Hg2+ concentration in the 37 nM–1 μM range.

Fluorescence properties and stimulated emission in substituted europium chelates

1967 ◽  
Vol 64 ◽  
pp. 173-182 ◽  
Author(s):  
Erhard J. Schimitschek ◽  
Richard B. Nehrich Jr ◽  
John A. Trias
Keyword(s):  
Stimulated Emission ◽  
Fluorescence Properties ◽  
Europium Chelates

RELATION BETWEEN THE STRIATION AND THE STIMULATED EMISSION IN A He-Ne LASER

1979 ◽  
Vol 40 (C7) ◽  
pp. C7-389-C7-390
Author(s):  
H. Amemiya ◽  
T. Dote ◽  
S. Kawamoto
Keyword(s):  
Stimulated Emission

Laser Oscillation in Aggregates of Ultrasmall Si Nanoparticles

2002 ◽  
Vol 728 ◽  
Author(s):  
Munir H. Nayfeh
Keyword(s):  
Stimulated Emission ◽  
Gaussian Beams ◽  
Single Particles ◽  
Nonlinear Characteristics ◽  
Femtosecond Radiation ◽  
Highly Nonlinear ◽  
Line Narrowing ◽  
Si Nanoparticles ◽  
Speckle Patterns ◽  
Spectral Line Narrowing

AbstractWe dispersed electrochemically etched Si into ultrabright ultrasmall nanoparticles, with brightness higher than fluorescein or rhodamine. The emission from single particles is readily detectable. Aggregates or films of the particles exhibit emission with highly nonlinear characteristics. We observe directed blue beams at ∼ 410 nm between faces of aggregates excited by femtosecond radiation at 780 nm; and at ∼ 610 nm from aggregates of red luminescent Si nanoparticles excited by radiation at 550-570 nm from a mercury lamp. Intense directed Gaussian beams, a pumping threshold, spectral line narrowing, and speckle patterns manifest the emission. The results are analyzed in terms of population inversion and stimulated emission in quantum confinement-induced Si-Si dimer phase, found only on ultrasmall Si nanoparticles. This microlasing constitutes an important step towards the realization of a laser on a chip.

Probing the Structural Features and the Micro-heterogeneity of Various Deep Eutectic Solvents and their Water Dilutions by the Photophysical Behaviour of Two Fluorophores

2020 ◽  
Author(s):  
Matteo Tiecco ◽  
Irene Di Guida ◽  
Pier Luigi Gentili ◽  
Raimondo Germani ◽  
Carmela Bonaccorso ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transient Absorption ◽  
Photophysical Properties ◽  
Deep Eutectic Solvents ◽  
Structural Features ◽  
Solvation Dynamics ◽  
Structured Systems ◽  
Reduced Viscosity ◽  
Bond Network ◽  
Fluorescent Molecules

<div><div><div><p>The structural features of a series of diverse Deep Eutectic Solvents (DESs) have been investigated and characterized by means of two fluorescent probes. The spectral and photophysical properties of the latter are strictly dependent on the experienced environment, so that they can provide insights into the polarity, viscosity, hydrogen-bond network, and micro-heterogeneity of the various DESs.</p><p>In fact, the investigated DESs exhibit a variety of properties with regards to their hydrophilicity, acidity, and hydrogen-bond ability, and these details were deeply probed by the two fluorescent molecules. The effect of the addition of water, which is a key strategy for tuning the properties of these structured systems, was also tested. In particular, the excited state dynamics of the probes, measured by femtosecond-resolved transient absorption, proved instrumental in understanding the changes in the structural properties of the DESs, namely reduced viscosity and enhanced heterogeneity, as the water percentage increases. Differences between the various DESs in terms of both local microheterogeneity and bulk viscosity also emerged from the peculiar multi-exponential solvation dynamics undergone by the excited states of the probes.</p></div></div></div>

Probing the Structural Features and the Micro-heterogeneity of Various Deep Eutectic Solvents and their Water Dilutions by the Photophysical Behaviour of Two Fluorophores

2020 ◽  
Author(s):  
Matteo Tiecco ◽  
Irene Di Guida ◽  
Pier Luigi Gentili ◽  
Raimondo Germani ◽  
Carmela Bonaccorso ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transient Absorption ◽  
Photophysical Properties ◽  
Deep Eutectic Solvents ◽  
Structural Features ◽  
Solvation Dynamics ◽  
Structured Systems ◽  
Reduced Viscosity ◽  
Bond Network ◽  
Fluorescent Molecules

<div><div><div><p>The structural features of a series of diverse Deep Eutectic Solvents (DESs) have been investigated and characterized by means of two fluorescent probes. The spectral and photophysical properties of the latter are strictly dependent on the experienced environment, so that they can provide insights into the polarity, viscosity, hydrogen-bond network, and micro-heterogeneity of the various DESs.</p><p>In fact, the investigated DESs exhibit a variety of properties with regards to their hydrophilicity, acidity, and hydrogen-bond ability, and these details were deeply probed by the two fluorescent molecules. The effect of the addition of water, which is a key strategy for tuning the properties of these structured systems, was also tested. In particular, the excited state dynamics of the probes, measured by femtosecond-resolved transient absorption, proved instrumental in understanding the changes in the structural properties of the DESs, namely reduced viscosity and enhanced heterogeneity, as the water percentage increases. Differences between the various DESs in terms of both local microheterogeneity and bulk viscosity also emerged from the peculiar multi-exponential solvation dynamics undergone by the excited states of the probes.</p></div></div></div>

Recent Advances on Amplified Stimulated Emission of Lead Halide Perovskite Micro/Nanostructures

2020 ◽  
Vol 41 (12) ◽  
pp. 1479-1489
Author(s):  
Ling HUANG ◽  
◽  
Hao DONG ◽  
Feng-yan JIA ◽  
Ling-dong SUN ◽  
...  
Keyword(s):  
Stimulated Emission ◽  
Recent Advances ◽  
Halide Perovskite ◽  
Amplified Stimulated Emission ◽  
Lead Halide
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