Low temperature inversion of optically detected electron spin resonance spectra due to different rates of electron tunneling for singlet and triplet radical–ion pairs

1994 ◽  
Vol 100 (5) ◽  
pp. 3476-3496 ◽  
Author(s):  
A. B. Doktorov ◽  
O. B. Spirina ◽  
Yu. N. Molin
1982 ◽  
Vol 36 (1) ◽  
pp. 52-57 ◽  
Author(s):  
L. S. Singer ◽  
I. C. Lewis

The applications of electron spin resonance (ESR) to carbonaceous materials are reviewed. The stable paramagnetic species observed in the products of low-temperature pyrolysis are odd-alternate neutral free radicals, whereas the unpaired spins of higher temperature carbons and graphites are primarily conduction electrons. The variety of ESR properties and phenomena requires special attention to techniques of measurement and interpretations of results. The relevance to the carbonization process of the free radicals observed by ESR is also discussed.


1979 ◽  
Vol 57 (5) ◽  
pp. 600-602 ◽  
Author(s):  
K. S. Chen ◽  
T. Foster ◽  
J. K. S. Wan

Contact radical ion-pairs of ammonium and fluoro-substituted ketones were generated in photochemical systems and their here-to-fore elusive esr spectra were characterized.


The electron spin resonance and optical absorption spectra of crystals of KCl containing silver impurity ions were examined after the crystals had been X -irradiated at 77 °K. It is shown that the silver impurity ions act as traps for both electrons and positive holes. A description is given of the annealing behaviour of the crystals after low-temperature irradiation.


1994 ◽  
Vol 50 (24) ◽  
pp. 18034-18039 ◽  
Author(s):  
K. F. Dombrowski ◽  
U. Kaufmann ◽  
M. Kunzer ◽  
K. Maier ◽  
J. Schneider ◽  
...  

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