High order and local structure of water determined by microwave dielectric study

1993 ◽  
Vol 99 (12) ◽  
pp. 9874-9881 ◽  
Author(s):  
Satoru Mashimo ◽  
Nobuhiro Miura
2013 ◽  
Vol 337-338 ◽  
pp. 49-53
Author(s):  
Min Quan Kuang ◽  
Shao Yi Wu ◽  
Xian Fen Hu ◽  
Bo Tao Song

The Knight shifts and hyperfine structure constants of Tl2Ba2CuO6+yare theoretically studied from the high order perturbation formulas of these quantities for a tetragonally elongated octahedral 3d9cluster. The calculation results reveal good agreement with the observed values. The obvious anisotropies of the Knight shifts can be ascribed to the local tetragonal elongation of the Cu2+site. The results and the local structure of the system are discussed.


1999 ◽  
Vol 230 (1) ◽  
pp. 157-162 ◽  
Author(s):  
Asako Oka ◽  
Ryusuke Nozaki ◽  
Yoichi Shiozaki

Biopolymers ◽  
1994 ◽  
Vol 34 (3) ◽  
pp. 357-364 ◽  
Author(s):  
Nobuhiro Miura ◽  
Nobuyuki Asaka ◽  
Naoki Shinyashiki ◽  
Satoru Mashimo

1989 ◽  
Vol 93 (12) ◽  
pp. 4963-4967 ◽  
Author(s):  
Satoru Mashimo ◽  
Toshihiro Umehara ◽  
Shinichi Kuwabara ◽  
Shin Yagihara

2014 ◽  
Vol 10 (4) ◽  
pp. 2558-2574 ◽  
Author(s):  
Anis. GHAZOUANI ◽  
Sondes. BOUGHAMMOURA ◽  
Jalel M'HALLA

In this paper, we propose a new approach in order to interpret the variation of the conductibility of the PSS polyion with the nature and the concentration of the alkaline counter-ions Li+, Na+ and K+, and the hydrophobic cations Et4N+ and Bu4N+. This approach is based on a recent model in which the stretched polyion is represented by a chain of successive charged spheres, partially condensed by the counter-ions. We have found that the moderate variation of the hydrodynamic friction on the polyion with the size RM of condensed counter-ions, cannot completely explain the important decrease (of about 35% from K+ to Bu4N+) of the conductibility (lPSS,M ) of the PSS polyion with the nature of the counter-ions. Consequently, we have proposed a supplementary explanation by taking into account of the translational dielectric friction on the moving polyion. Formal analysis of this friction shows that it is very sensitive to the local structure of water surrounding the polyions. As this local structure depends in its turn, on the nature of the condensed counter-ions; we suggested that this specific sensitivity could explain the high dependence of the mobility of the polyion with the nature of its counter-ions.    


2010 ◽  
Vol 81 (12) ◽  
Author(s):  
Alexandre Langlois ◽  
Mario Poirier ◽  
Claude Bourbonnais ◽  
Pascale Foury-Leylekian ◽  
Alec Moradpour ◽  
...  

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