Crystal‐field excitations and magnetic properties of TmPO4

1993 ◽  
Vol 98 (5) ◽  
pp. 4214-4222 ◽  
Author(s):  
C.‐K. Loong ◽  
L. Soderholm ◽  
M. M. Abraham ◽  
L. A. Boatner ◽  
N. M. Edelstein
Keyword(s):  
Magnetic Properties ◽  
Crystal Field

THE COMBINED ANALYSIS OF SPECIFIC HEAT AND THERMAL EXPANSION OF Nd1−xLuxMn2 COMPOUNDS

1993 ◽  
Vol 07 (01n03) ◽  
pp. 810-813
Author(s):  
N.H. KIM-NGAN ◽  
P.E. BROMMER ◽  
J.J.M. FRANSE
Keyword(s):  
Magnetic Properties ◽  
Thermal Expansion ◽  
Thermodynamic Properties ◽  
Specific Heat ◽  
Crystal Field ◽  
Spin Fluctuation ◽  
Spin Reorientation ◽  
Antiferromagnetic Order ◽  
Combined Analysis ◽  
Temperature Range

Specific heat and thermal expansion measurements have been performed on Nd1−xLUxMn2 in the temperature range between 1.5K and 300K. Below 10K, anomalies are observed which are ascribed to a spin reorientation of the Nd sublattice. These anomalies are only slightly affected by the substitution of Nd by Lu. Large effects, however, are observed on the magnetic properties of the Mn sublattice. The antiferromagnetic order disappears for x exceeding 0.30. The data are analysed in terms of Grüneisen parameters. In the paramagnetic compound LuMn2, a spin-fluctuation contribution to the thermodynamic properties is observed. In the Nd-containing compounds, distinct contributions from the crystal field acting on the Nd ions can be distinguished. The variation of the magnetic properties of the Mn sublattice with the concentration of Lu is discussed.

Comment on “Crystal Field Model of the Magnetic Properties of URu2Si2”

1995 ◽  
Vol 74 (20) ◽  
pp. 4097-4097 ◽  
Author(s):  
M. B. Walker ◽  
W. J. L. Buyers
Keyword(s):  
Magnetic Properties ◽  
Crystal Field ◽  
Field Model

Crystal field influence on the magnetic properties of RNi5 compounds

1988 ◽  
Vol 76-77 ◽  
pp. 187-188 ◽  
Author(s):  
P.C.M. Gubbens ◽  
A.M. Van der Kraan ◽  
K.H.J. Buschow
Keyword(s):  
Magnetic Properties ◽  
Crystal Field ◽  
Field Influence

Magnetische Eigenschaften der Normaltemperaturform von CsTmO2 / Magnetic Properties of the Normal-Temperature Form of CsTmO2

1979 ◽  
Vol 34 (8) ◽  
pp. 997-1002 ◽  
Author(s):  
Werner Urland
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Crystal Field ◽  
Ground State ◽  
Low Temperatures ◽  
Magnetic Behaviour ◽  
Magnetic Data ◽  
Angular Overlap Model ◽  
Temperature Form ◽  
Overlap Model

AbstractThe magnetic behaviour of the normal-temperature-form of CsTmO2 (NT-CsTmO2) has been studied in the temperature range between 2.9 and 251.3 K. In order to interpret the magnetic data a method applying the angular overlap model has been established to assess the crystal-field (CF) parameters of NT-CsTmO2 (CF symmetry: D3d) from the known CF parameters for Tm3+ substituted in YVO4 (CF symmetry: D2d)-With these CF parameters the observed magnetic properties of NT-CsTmO2 can be satisfactorily simulated. The calculation of the paramagnetic principal susceptibilities yields a high magnetic anisotropy, especially at low temperatures. The energy values of the CF levels of the 3H6 ground state are calculated.

Magnetic properties of the mixed spin-5/2 and spin-3/2 Blume-Capel Ising system on the two-fold Cayley tree

Open Physics ◽  
2009 ◽  
Vol 7 (3) ◽  
Author(s):  
Rachidi Yessoufou ◽  
Saliou Amoussa ◽  
Felix Hontinfinde
Keyword(s):  
Magnetic Properties ◽  
Phase Transitions ◽  
Crystal Field ◽  
Cayley Tree ◽  
Second Order ◽  
Coordination Numbers ◽  
First Order ◽  
Mixed Spin ◽  
Second Order Transition ◽  
Zero Values

AbstractWe use exact recursion relations to study the magnetic properties of the half-integer mixed spin-5/2 and spin-3/2 Blume-Capel Ising ferromagnetic system on the two-fold Cayley tree that consists of two sublattices A and B. Two positive crystal-field interactions Δ1 and Δ2 are considered for the sublattice with spin-5/2 and spin-3/2 respectively. For different coordination numbers q of the Cayley tree sites, the phase diagrams of the model are presented with a special emphasis on the case q = 3, since other values of q reproduce similar results. First, the T = 0 phase diagram is illustrated in the (D A = Δ1/J,D B = Δ2/J) plane of reduced crystal-field interactions. This diagram shows triple points and coexistence lines between thermodynamically stable phases. Secondly, the thermal variation of the magnetization belonging to each sublattice for some coordination numbers q are investigated as well as the Helmoltz free energy of the system. First-order and second-order phase transitions are found. The second-order phase transitions become sharper and sharper when D A or D B increases. The first-order transitions only exist for some appropriate non-zero values of D A and/or D B. The corresponding transition lines never connect to the second-order transition lines. Thus, the non-existence of tricritical points remains one of the key features of the present model. The magnetic exponent β 0 of the model is estimated and found to be ¼ at small values of D A = D B = D and β 0 = ½ at large values of D. At intermediate values of D, there is a crossover region where the magnetic exponent displays interesting behaviours.

Abinitiocalculation of electronic structure, crystal field, and intrinsic magnetic properties ofSm2Fe17,Sm2Fe17N3,Sm2Fe17C3, andSm2Co17

1996 ◽  
Vol 53 (11) ◽  
pp. 7111-7127 ◽  
Author(s):  
Lutz Steinbeck ◽  
Manuel Richter ◽  
Ulrike Nitzsche ◽  
Helmut Eschrig
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
Crystal Field
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