Calculation of planewise dipole sums for anthracene crystal

1992 ◽  
Vol 97 (6) ◽  
pp. 4536-4542 ◽  
Author(s):  
S. E. Mothersdale ◽  
R. W. Munn
Keyword(s):  
Anthracene Crystal ◽  
Dipole Sums

Electrochemistry at anthracene crystal/aqueous nitrite, nitrate solution interface

1988 ◽  
Vol 92 (9) ◽  
pp. 2506-2511
Author(s):  
Baldwin Leong ◽  
Martin Pope ◽  
Joseph Steigman
Keyword(s):  
Nitrate Solution ◽  
Solution Interface ◽  
Anthracene Crystal ◽  
Nitrite Nitrate

Impurity induced phosphorescence in anthracene crystal

1975 ◽  
Vol 30 (1) ◽  
pp. 5-10 ◽  
Author(s):  
A. Brillante ◽  
D.P. Craig ◽  
A.W.-H. Mau ◽  
J. Rajikan
Keyword(s):  
Anthracene Crystal

Sub-Second Tracing of Lattice Mode Changes During the Melting of an Anthracene Crystal

2010 ◽  
Author(s):  
Hajime Okajima ◽  
Hiro-o Hamaguchi ◽  
P. M. Champion ◽  
L. D. Ziegler
Keyword(s):  
Lattice Mode ◽  
Anthracene Crystal

Molecular Vibrations in the Exciton Theory for Molecular Aggregates. V. Electronic Spectra of Weakly-coupled Systems

1963 ◽  
Vol 16 (3) ◽  
pp. 315 ◽  
Author(s):  
EG McRae
Keyword(s):  
Electronic Spectra ◽  
Fluorescence Spectra ◽  
Vibrational Structure ◽  
Coupled Systems ◽  
Quantum Yields ◽  
Molecular Aggregates ◽  
Relative Quantum ◽  
Electronically Excited ◽  
Anthracene Crystal ◽  
Theoretical Results

The theory of the gross vibrational structure in the electronic spectra of molecular aggregates is developed for the case of weak intermolecular interaction. The electronically excited states are represented by a set of m-m functions corrected to first order as described in Part IV of this series. An explicit treatment is given for aggregates with two molecules per unit cell. Formulae are obtained for the relative vibronic intensities, splittings, and polarization ratios in absorption spectra, and for relative quantum yields and polarization ratios in fluorescence spectra. The theoretical results are compared with those of the E-V coupling theory developed in Parts II and III. On the basis of this comparison, a general equation is put forward to relate the theoretical crystal splitting (i.e. the splitting for a rigid model) to observed polarization ratios in spectra. The theoretical results are compared with the observed vibrational structure in the 3800 Ǻ band system of anthracene crystal. The crystal splitting calculated from the observed polarization ratios is 380 cm-1. The theory accounts, within the rather large experimental error, for the observed variations of polarization ratio in both the absorption and the fluorescence spectra of anthracene crystal.

Dipole oscillator strength distributions, sums, and some related properties for Li, N, O, H2, N2, O2, NH3, H2O, NO, and N2O

1977 ◽  
Vol 55 (23) ◽  
pp. 2080-2100 ◽  
Author(s):  
G. D. Zeiss ◽  
William J. Meath ◽  
J. C. F. MacDonald ◽  
D. J. Dawson
Keyword(s):  
Oscillator Strength ◽  
Cross Sections ◽  
High Energy ◽  
High Energy Electron ◽  
Sum Rule ◽  
Dipole Oscillator ◽  
Scattering Cross Sections ◽  
Additional Constraints ◽  
Dipole Sums ◽  
Strength Distributions

Dipole oscillator strength distributions (DOSDs) have been constructed for ground state Li, N, O, H2, N2, O2, NH3, H2O, NO, and N2O by using experimental and theoretical photoabsoiption and high energy electron inelastic scattering cross sections. Each DOSD is required to satisfy the Thomas–Reiche–Kuhn sum rule and additional constraints derived from available accurate experimental refractivity and dispersion measurements. The DOSDs, the data and procedure used to construct the DOSDs, and the values of the dipole oscillator strength sums Sk and Lk (for a variety of k values) and related atomic and molecular properties obtained from the DOSDs are reported. The discussion includes comments regarding the importance of the constraints imposed on the DOSD with respect to the evaluation of various dipole sums and properties and the accuracy of the results.

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