Potential of mean force for an aqueous chloride ion pair: Simulation with a polarizable model

1992 ◽  
Vol 96 (12) ◽  
pp. 9237-9238 ◽  
Author(s):  
Omar A. Karim
Keyword(s):  
Chloride Ion ◽  
Ion Pair ◽  
Potential Of Mean Force ◽  
Aqueous Chloride

Electrochemical Performance of Sb4O5Cl2 as a New Anode Material in Aqueous Chloride-Ion Battery

2019 ◽  
Vol 11 (9) ◽  
pp. 9144-9148 ◽  
Author(s):  
Xiaoqiao Hu ◽  
Fuming Chen ◽  
Shaofeng Wang ◽  
Qiang Ru ◽  
Benli Chu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Anode Material ◽  
Chloride Ion ◽  
Aqueous Chloride

Solvation structure of a sodium chloride ion pair in water

1986 ◽  
Vol 108 (8) ◽  
pp. 1755-1761 ◽  
Author(s):  
Alan C. Belch ◽  
Max. Berkowitz ◽  
J. A. McCammon
Keyword(s):  
Sodium Chloride ◽  
Chloride Ion ◽  
Ion Pair ◽  
Solvation Structure

scholarly journals 5-Acetyl-4-(3-hydroxyphenyl)-6-methyl-1,2,3,4-tetrahydropyrimidin-2-one–tris(hydroxymethyl)ammonium chloride (2/1)

2013 ◽  
Vol 69 (12) ◽  
pp. o1766-o1767 ◽  
Author(s):  
C. A. M. A. Huq ◽  
S. Fouzia ◽  
M. NizamMohideen
Keyword(s):  
Hydrogen Bonds ◽  
Ammonium Chloride ◽  
Three Dimensional ◽  
Chloride Ion ◽  
Chair Conformation ◽  
Pyrimidine Ring ◽  
Pyrimidine Derivative ◽  
Ion Pair ◽  
Framework Structure ◽  
Pyrimidine Derivatives

The asymmetric unit of the title compound, 2C13H14N2O3·C3H10NO3+·Cl−, contains two independent molecules (AandB) of the title pyrimidine derivative and one ion-pair of tris(hydroxymethyl)ammonium chloride. The pyrimidine ring in each pyrimidine derivative has a half-chair conformation. Its mean plane is inclined to the benzene ring by 87.2 (3)° in moleculeAand 85.7 (2)° in moleculeB. In the crystal, the pyrimidine derivatives are connected to each other by N—H...O hydrogen bonds, forming chains propagating along theb-axis direction. The chains are linkedviaO—H—Cl hydrogen bonds, forming corrugated sheets lying parallel to thebcplane. The sheets are linkedviaC—H...O hydrogen bonds, forming a three-dimensional framework. The tris(hydroxymethyl)ammonium chloride molecules are located in the cages of the framework. There are also further C—H...O hydrogen bonds and C—H...π interactions present in the three-dimensional framework structure. Both the cation and chloride anion of the tris(hydroxymethyl)ammonium chloride ion pair are disordered over two positions, with a refined occupancy ratio of 0.418 (8):0.582 (8) for the cation and 0.71 (4):0.29 (4) for the anion.

Protodemercuration of organomercuric chlorides. II. Heterocyclic mercuric chlorides

1965 ◽  
Vol 18 (10) ◽  
pp. 1513 ◽  
Author(s):  
RD Brown ◽  
AS Buchanan ◽  
AA Humffray
Keyword(s):  
Chloride Ion ◽  
Ion Pair ◽  
Zero Order ◽  
Hydrogen Ion ◽  
First Order ◽  
Entropy Effects ◽  
Kinetics Of ◽  
Complex Anions ◽  
Dominant Influence ◽  
Electron Effects

The kinetics of protodemercuration, or displacement of the HgCl group by hydrogen, have been measured for 2- and 3-furyl, 2-thienyl, and 2-selenophenylmercuric chlorides. The reactions of these compounds with aqueous alcoholic hydrochloric acid were first order in hydrogen ion, first order in RHgC1, and zero order in chloride ion, when the latter was present at concentrations less than 0.1M. At 70�, the relative rates were: 3-furyl, 1; 2-furyl, 27; 2-thienyl, 11; 2-seleno- phenyl, 25. At higher chloride concentrations, the rate increases; this is discussed in terms of formation of complex anions of the type RHgCl32- and in terms of H+Cl- ion pair attack. The dominant influence of entropy effects in the case of furan compounds emphasizes the danger of trying to account for observed relative rates in terms of π-electron effects alone.

Sb nanoparticle decorated rGO as a new anode material in aqueous chloride ion batteries

Nanoscale ◽  
2020 ◽  
Vol 12 (23) ◽  
pp. 12268-12274 ◽  
Author(s):  
Qi Zhang ◽  
R. Karthick ◽  
Xiliang Zhao ◽  
Liguo Zhang ◽  
Yumeng Shi ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Uniform Distribution ◽  
Reduced Graphene Oxide ◽  
Anode Material ◽  
High Capacity ◽  
Chloride Ion ◽  
Reduced Graphene ◽  
One Step ◽  
Aqueous Chloride ◽  
Graphene Oxide Sheets

Antimony nanoparticle decorated reduced graphene oxide sheets with uniform distribution were synthesized as a new anode of aqueous chloride ion batteries in one step, which demonstrates a high capacity, and excellent reversibility and stability.

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