Partial structure factors in colloidal silica mixtures determined with small‐angle neutron scattering contrast variation

1991 ◽  
Vol 94 (6) ◽  
pp. 4521-4531 ◽  
Author(s):  
M. H. G. Duits ◽  
R. P. May ◽  
A. Vrij ◽  
C. G. de Kruif
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Colloidal Silica ◽  
Partial Structure ◽  
Contrast Variation ◽  
Structure Factors

Ultra-Small-Angle Neutron Scattering Study of Colloidal Alloys. 1. Contrast Variation Experiments for Mixtures of Hydrogenated and Deuterated Polystyrene Latices in H2O/D2O

Langmuir ◽  
1999 ◽  
Vol 15 (2) ◽  
pp. 293-296 ◽  
Author(s):  
Hideki Matsuoka ◽  
Takashi Ikeda ◽  
Hitoshi Yamaoka ◽  
Mitsuhiro Hashimoto ◽  
Toshio Takahashi ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Contrast Variation ◽  
Scattering Study ◽  
Neutron Scattering Study

Mechanically Interlocked Structure of Polyrotaxane Investigated by Contrast Variation Small-Angle Neutron Scattering

2009 ◽  
Vol 42 (16) ◽  
pp. 6327-6329 ◽  
Author(s):  
Koichi Mayumi ◽  
Hitoshi Endo ◽  
Noboru Osaka ◽  
Hideaki Yokoyama ◽  
Michihiro Nagao ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Contrast Variation

Small angle neutron scattering experiments on nanostructured matter using contrast variation

1997 ◽  
Vol 9 (1-8) ◽  
pp. 327-330
Author(s):  
S. Janßen ◽  
J. Wagner ◽  
H. Natter ◽  
J. Prewo ◽  
R. Rupp ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Contrast Variation

Structure of Nanocomposite Hydrogel Investigated by Means of Contrast Variation Small-Angle Neutron Scattering

2008 ◽  
Vol 41 (14) ◽  
pp. 5406-5411 ◽  
Author(s):  
Hitoshi Endo ◽  
Sho Miyazaki ◽  
Kazutoshi Haraguchi ◽  
Mitsuhiro Shibayama
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Nanocomposite Hydrogel ◽  
Contrast Variation

scholarly journals Amphiphilic Comb Polymers as New Additives in Bicontinuous Microemulsions

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2410
Author(s):  
Debasish Saha ◽  
Karthik R. Peddireddy ◽  
Jürgen Allgaier ◽  
Wei Zhang ◽  
Simona Maccarrone ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Amphiphilic Polymers ◽  
Side Chain ◽  
Side Chains ◽  
Contrast Variation ◽  
Dna Complexes ◽  
Comb Polymers ◽  
Polymer Architectures

It has been shown that the thermodynamics of bicontinuous microemulsions can be tailored via the addition of various different amphiphilic polymers. In this manuscript, we now focus on comb-type polymers consisting of hydrophobic backbones and hydrophilic side chains. The distinct philicity of the backbone and side chains leads to a well-defined segregation into the oil and water domains respectively, as confirmed by contrast variation small-angle neutron scattering experiments. This polymer–microemulsion structure leads to well-described conformational entropies of the polymer fragments (backbone and side chains) that exert pressure on the membrane, which influences the thermodynamics of the overall microemulsion. In the context of the different polymer architectures that have been studied by our group with regards to their phase diagrams and small-angle neutron scattering, the microemulsion thermodynamics of comb polymers can be described in terms of a superposition of the backbone and side chain fragments. The denser or longer the side chain, the stronger the grafting and the more visible the brush effect of the side chains becomes. Possible applications of the comb polymers as switchable additives are discussed. Finally, a balanced philicity of polymers also motivates transmembrane migration in biological systems of the polymers themselves or of polymer–DNA complexes.

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