Charge and electrical potential distributions in a nonequilibrium inhomogeneous electrolyte solution. A statistical mechanical approach. I. Single binary electrolyte. Theory

1991 ◽  
Vol 94 (9) ◽  
pp. 6135-6146 ◽  
Author(s):  
Fernando O. Raineri ◽  
Harold L. Friedman
Keyword(s):  
Electrolyte Solution ◽  
Electrical Potential ◽  
Mechanical Approach ◽  
Statistical Mechanical

Statistical mechanical approach to Fukui-Ishibashi traffic flow models

1998 ◽  
Vol 57 (3) ◽  
pp. 2568-2573 ◽  
Author(s):  
Bing-Hong Wang ◽  
Yvonne-Roamy Kwong ◽  
Pak-Ming Hui
Keyword(s):  
Traffic Flow ◽  
Flow Models ◽  
Traffic Flow Models ◽  
Mechanical Approach ◽  
Statistical Mechanical

Kinetics of electrode processes in the presence of a discrete layer of a specifically adsorbed organic substance

1981 ◽  
Vol 59 (13) ◽  
pp. 2026-2030 ◽  
Author(s):  
V. S. Krylov ◽  
I. F. Fishtik
Keyword(s):  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Electrochemical Process ◽  
Adsorbed Species ◽  
Electrode Processes ◽  
Mechanical Approach ◽  
Statistical Mechanical ◽  
Kinetics Of ◽  
Theoretical Results ◽  
Discrete Layer

The problem of an adequate statistical mechanical approach to the transition from the description of the elementary act of an electrochemical process occurring in the presence of electrochemically inactive specifically adsorbed species to the description of the resulting heterogeneous process for which the rate is measured in experiments is discussed. The analysis of the electrode kinetics is given for the particular case where the irreversible electron transfer reaction at the metal/solution takes place in the presence of a fixed discrete layer of specifically adsorbed dipole molecules. The theoretical results are compared with the available experimental data on the influence of adsorbed organic substances on the electrochemical reaction rate.

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