Resonance‐enhanced multiphoton ionization‐photoelectron spectra of CO2. I. Photoabsorption above the ionization potential

1991 ◽  
Vol 94 (12) ◽  
pp. 7596-7601 ◽  
Author(s):  
Ming Wu ◽  
David P. Taylor ◽  
Philip M. Johnson
Keyword(s):  
Ionization Potential ◽  
Multiphoton Ionization ◽  
Photoelectron Spectra

scholarly journals Photoelectron spectra after multiphoton ionization of Li atoms in the one-photon Rabi-flopping regime

2019 ◽  
Vol 100 (2) ◽  
Author(s):  
D. A. Tumakov ◽  
Dmitry A. Telnov ◽  
G. Plunien ◽  
V. M. Shabaev
Keyword(s):  
Multiphoton Ionization ◽  
Photoelectron Spectra ◽  
The One

Photoelectron Spectra and Molecular Properties, XLVIII Carbonates and Thiocarbonates

1975 ◽  
Vol 30 (11-12) ◽  
pp. 862-874 ◽  
Author(s):  
K. Wittel ◽  
E. E. Astrup ◽  
H. Bock ◽  
G. Graeffe ◽  
H. Juslén
Keyword(s):  
Ionization Potential ◽  
Substituent Effects ◽  
Lone Pair ◽  
Emission Spectra ◽  
Low Energy ◽  
Photoelectron Spectra ◽  
Energy Bands ◽  
Open Chain ◽  
First Ionization Potential ◽  
Cndo Calculations

Photoelectron (PE) spectra of ethylene and vinylene carbonates and thiocarbonates as well as of methylene trithiocarbonate and some open-chain derivatives are reported.The low energy bands, well separated in the unsaturated compounds, are assigned to lone pair and π type ionizations. The assignment is based on comparison of PE spectra, modified CNDO calculations, and sulfur Κβ emission spectra. The pronounced substituent effects due to which the first ionization potential varies from 8.4 eV to 11.1 eV are discussed.

A Discussion on photoelectron spectroscopy - A study of the bonding in the group IV tetrahalides by photoelectron spectroscopy

1970 ◽  
Vol 268 (1184) ◽  
pp. 111-130 ◽  
Keyword(s):  
Ionization Potential ◽  
Molecular Orbital ◽  
Photoelectron Spectroscopy ◽  
Electronic Structures ◽  
Group Iv ◽  
Photoelectron Spectra

The photoelectron spectra excited by helium 21.2 eV radiation in the group IV halides, AB4, where A = C, Si, Ge, Sn, Ti and B = C1, Br, have been determined. The ionization potential data are discussed in terms of a simple molecular orbital description of the electronic structures.

Photoelectron spectroscopy of hydrogen-bonded systems: spectra of monomers, dimers and mixed complexes of carboxylic acids

1972 ◽  
Vol 331 (1585) ◽  
pp. 249-261 ◽  
Keyword(s):  
Hydrogen Bonding ◽  
Ionization Potential ◽  
Carboxylic Acids ◽  
Photoelectron Spectroscopy ◽  
Free Acid ◽  
Photoelectron Spectra ◽  
Target Chamber ◽  
Donor Group ◽  
Mixed Complexes ◽  
First Ionization Potential

By cooling the target chamber of a photoelectron spectrometer, the photoelectron spectra of dimers and mixed complexes of carboxylic acids have been obtained. By comparison of the spectra with each other and with those of the monomers, it has been possible to assign several bands to ionization from specific molecular orbitals. Hydrogen-bonding changes most ionization potentials of the monomers but not by more than about 0.5 eV. In particular, the ionization potential of an electron from a non-bonding orbital on the proton donor group is decreased and that from a non-bonding orbital on the electron donor group is increased. This is consistent with most theories of hydrogen bonding. In the mixed complexes it makes the first ionization potential higher than that of the free acids, dimers, however, are complicated by the initial degeneracy of their orbitals and this results in their first ionization potential being lower than for the free acid. There is also some evidence that the hydrogen bonds in a complex between different acids are of unequal strength.

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