The microwave spectrum of the equatorial conformer of chlorocyclopentane

1991 ◽  
Vol 94 (5) ◽  
pp. 3315-3321 ◽  
Author(s):  
P. Groner ◽  
Min Joo Lee ◽  
J. R. Durig
Keyword(s):  
Microwave Spectrum ◽  
Equatorial Conformer

Microwave spectrum of morpholine

1969 ◽  
Vol 47 (18) ◽  
pp. 3453-3462 ◽  
Author(s):  
J. J. Sloan ◽  
R. Kewley
Keyword(s):  
Dipole Moment ◽  
Vibrational State ◽  
Microwave Spectrum ◽  
Coupling Constants ◽  
Chair Conformer ◽  
Imino Group ◽  
Ground Vibrational State ◽  
Principal Axes ◽  
Quadrupole Coupling ◽  
Equatorial Conformer

The microwave spectra of morpholine and N-deuteromorpholine have been investigated within the 8 to 40 GHz region. For both the normal and the deuterated species, strong a-type spectra which are due to the chair conformer with an equatorial imino group were recorded. The ground vibrational state rotational constants and quadrupole coupling constants are (in MHz), for normal morpholine, A = 4924.88 ± 0.05, B = 4625.15 ± 0.05, C = 2684.25 ± 0.05, χaa = 2.22 ± 0.02, χbb = 2.51 ± 0.04, χcc = −4.73 ± 0.02, and for N-deuteromorpholine, A = 4925.39 ± 0.05, B = 4399.67 ± 0.05, C = 2607.09 ± 0.05, χaa = 1.92 ± 0.02, χbb = 2.59 ± 0.04, χcc = −4.51 ± 0.02. The rs coordinates of the imino hydrogen are (in Å) aH = 2.373 ± 0.005 and cH = 0.10 ± 0.03. For the normal species the dipole moment components are (in D) μa = 1.68 ± 0.01, μc = 0.30 ± 0.01, μ = 1.71 ± 0.02. The value of aH and the direction of μ with respect to the a and c principal axes confirm that the observed spectrum is that of the chair equatorial conformer of morpholine.

ChemInform Abstract: The Microwave Spectrum of the Equatorial Conformer of Chlorocyclopentane

ChemInform ◽  
2010 ◽  
Vol 22 (29) ◽  
pp. no-no
Author(s):  
P. GRONER ◽  
M. J. LEE ◽  
J. R. DURIG
Keyword(s):  
Microwave Spectrum ◽  
Equatorial Conformer

Microwave spectrum and structure of the (CO2)2N2O complex

1999 ◽  
Vol 96 (9) ◽  
pp. 1355-1365 ◽  
Author(s):  
REBECCA A. PEEBLES, SEAN A. PEEBLES, ROBERT
Keyword(s):  
Microwave Spectrum

The microwave spectrum of BrF5 in excited vibrational states

1978 ◽  
Vol 72 (2) ◽  
pp. 282-292 ◽  
Author(s):  
C. Gheorghiou ◽  
P.N. Brier ◽  
J.G. Baker ◽  
S.R. Jones
Keyword(s):  
Microwave Spectrum ◽  
Vibrational States

Microwave spectrum, dipole moment, and conformation of ethanedithiol

1984 ◽  
Vol 81 (2) ◽  
pp. 1051-1053 ◽  
Author(s):  
R. N. Nandi ◽  
Chun‐Fu Su ◽  
Marlin D. Harmony
Keyword(s):  
Dipole Moment ◽  
Microwave Spectrum
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