Interaction induced contributions to the far infrared spectrum of a polar fluid: Zeroth and second spectral moments

1990 ◽  
Vol 93 (11) ◽  
pp. 7561-7565
Author(s):  
Pancracio Palting ◽  
Jeanne L. McHale
1981 ◽  
Vol 59 (10) ◽  
pp. 1448-1458 ◽  
Author(s):  
J. D. Poll ◽  
J. L. Hunt

The far infrared collision-induced spectrum of N2 gas at 300 and 124 K is analysed using an empirical lineshape function. The theory of the collision-induced spectrum of N2 is developed and expressions are derived for the first and second spectral moments in the cases of quadrupolar, hexadecapolar, and for L = 1 and L = 3 overlap induction. The spectra are then reconstructed with various combinations of these mechanisms in order to determine the best values and probable ranges of the quadrupole and hexadecapole moments and the strength of the overlap moments. We find an excellent fit for a value of the quadrupole moment that agrees with that found by Buckingham, QB = −(1.09 ± 0.05)ea02, with overlap dipole parameters λ1 = ± 1 × 10−3ea0, λ3 = 1 × 10−3ea0, and an effective hexadecapole moment Φ = −(10.4 ± 1)ea04.


1988 ◽  
Vol 49 (11) ◽  
pp. 1901-1910 ◽  
Author(s):  
F. Masset ◽  
L. Lechuga-Fossat ◽  
J.-M. Flaud ◽  
C. Camy-Peyret ◽  
J.W.C. Johns ◽  
...  

1987 ◽  
Vol 126 (2) ◽  
pp. 443-459 ◽  
Author(s):  
Nobukimi Ohashi ◽  
Kojiro Takagi ◽  
Jon T. Hougen ◽  
W.Bruce Olson ◽  
Walter J. Lafferty

1980 ◽  
Vol 35 (3) ◽  
pp. 229-232 ◽  
Author(s):  
Th. Rasing ◽  
J.H.M. Stoelinga ◽  
P. Wyder

1973 ◽  
Vol 45 (1) ◽  
pp. 55-64 ◽  
Author(s):  
Llewellyn H. Jones

1986 ◽  
Vol 84 (3) ◽  
pp. 1935-1937 ◽  
Author(s):  
K. R. Leopold ◽  
L. R. Zink ◽  
K. M. Evenson ◽  
D. A. Jennings ◽  
M. Mizushima

1966 ◽  
Vol 45 (8) ◽  
pp. 3141-3147 ◽  
Author(s):  
Robert H. Hunt ◽  
Robert A. Leacock

1969 ◽  
Vol 50 (1) ◽  
pp. 351-353 ◽  
Author(s):  
A. Lightman ◽  
A. Ben‐Reuven

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