Photodissociation of iodine complexes in relation to the cage effect

1990 ◽  
Vol 93 (12) ◽  
pp. 8676-8681 ◽  
Author(s):  
Jean‐Michel Philippoz ◽  
René Monot ◽  
Hubert van den Bergh
Keyword(s):  
Cage Effect ◽  
Iodine Complexes

Characterization and Conductivities of Polyphosphazene-Iodine Complexes

1991 ◽  
Author(s):  
Michael M. Lerner ◽  
Andrew L. Tipton ◽  
Duward F. Shriver ◽  
Alexa A. Dembek ◽  
Harry R. Allcock
Keyword(s):  
Iodine Complexes

Ionic dissociation in complexes of iodine with triphenylarsine and triphenylstibine

1991 ◽  
Vol 69 (4) ◽  
pp. 606-610 ◽  
Author(s):  
Ying Ru Zhang ◽  
Ira Solomon ◽  
Seymour Aronson
Keyword(s):  
Complex Formation ◽  
Chemical Nature ◽  
Equilibrium Constants ◽  
Electrochemical Technique ◽  
High Iodine ◽  
Ionic Complex ◽  
Ionization Mechanisms ◽  
Iodine Complex ◽  
Ionic Dissociation ◽  
Iodine Complexes

An electrochemical technique has been employed to study the ionization of the iodine complexes of (C6H5)3As, (C6H5)3Sb, and pyridine. Several different ionization mechanisms are proposed depending on the chemical nature and concentration of the reactants. A new ionic complex, (C6H5)3MI22+ is postulated for the interaction of iodine with (C6H5)3As and (C6H5)3Sb at high iodine concentrations. Equilibrium constants have been calculated from the emf data for the various ionization steps. Key words: triphenylarsine, triphenylstibine, iodine, complex formation, ionization.

Study of the Infrared Absorption Spectra of Some Pyridine Derivatives-Iodine Complexes

1976 ◽  
Vol 30 (2) ◽  
pp. 200-204 ◽  
Author(s):  
F. M. Abdel Kerim ◽  
F. Abou El Fotouh
Keyword(s):  
Complex Formation ◽  
Absorption Spectra ◽  
Infrared Absorption ◽  
Ir Absorption ◽  
Pyridine Derivatives ◽  
Thermodynamic Constants ◽  
Ir Absorption Spectra ◽  
Infrared Absorption Spectra ◽  
The Stability ◽  
Iodine Complexes

The ir absorption spectra of some pyridine derivatives-iodine complexes were measured in the region 400 to 1400 cm−1 and the results are discussed. The effect of complex formation on the intensities of some of the bands was investigated. The thermodynamic constants of these complexes were calculated. It was found that the stability of the complex depends to a large extent on the electronegativity as well as the position of the substituent on the pyridine nucleus. The structures of formed complexes are discussed.

Characterization and conductivities of polyphosphazene-iodine complexes

1991 ◽  
Vol 3 (6) ◽  
pp. 1117-1120 ◽  
Author(s):  
Michael M. Lerner ◽  
Andrew L. Tipton ◽  
Duward F. Shriver ◽  
Alexa A. Dembek ◽  
Harry R. Allcock
Keyword(s):  
Iodine Complexes

The one-atom cage effect in I2(B)–Ar: Evidence that caging is inefficient for the T-shaped isomer

1999 ◽  
Vol 111 (6) ◽  
pp. 2478-2483 ◽  
Author(s):  
Amy Burroughs ◽  
Todd Van Marter ◽  
Michael C. Heaven
Keyword(s):  
Cage Effect ◽  
The One
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