A generic test of gas phase isolated binary collision theories for vibrational relaxation at liquid state densities based on the rescaling properties of collision frequencies

1990 ◽  
Vol 93 (5) ◽  
pp. 3712-3713 ◽  
Author(s):  
M. E. Paige ◽  
C. B. Harris
Keyword(s):  
Gas Phase ◽  
Vibrational Relaxation ◽  
Liquid State ◽  
Binary Collision ◽  
State Densities

scholarly journals Kinetically Trapped Liquid-State Conformers of a Sodiated Model Peptide Observed in the Gas Phase

2017 ◽  
Vol 121 (36) ◽  
pp. 6838-6844 ◽  
Author(s):  
Markus Schneider ◽  
Chiara Masellis ◽  
Thomas Rizzo ◽  
Carsten Baldauf
Keyword(s):  
Gas Phase ◽  
Liquid State ◽  
Model Peptide

Binary-collision-induced longitudinal relaxation in gas-phase Kr83

2008 ◽  
Vol 129 (24) ◽  
pp. 244304 ◽  
Author(s):  
Zackary I. Cleveland ◽  
Thomas Meersmann
Keyword(s):  
Gas Phase ◽  
Binary Collision ◽  
Longitudinal Relaxation

scholarly journals Vibrational relaxation of CH3I in the gas phase and in solution

2004 ◽  
Vol 120 (15) ◽  
pp. 6973-6979 ◽  
Author(s):  
Christopher G. Elles ◽  
M. Jocelyn Cox ◽  
F. Fleming Crim
Keyword(s):  
Gas Phase ◽  
Vibrational Relaxation

Electrostatic interactions as a factor in the determination of the HOMO in the liquid state

1986 ◽  
Vol 64 (12) ◽  
pp. 2353-2358 ◽  
Author(s):  
Enrique Sánchez Marcos ◽  
Joaquín Maraver ◽  
Manuel F. Ruíz-López ◽  
Juan Bertrán
Keyword(s):  
Gas Phase ◽  
Molecular Orbital ◽  
Perturbation Analysis ◽  
Liquid State ◽  
Electrostatic Interactions ◽  
Orbital Evolution ◽  
Benzene Derivatives ◽  
Cavity Model ◽  
Ellipsoidal Cavity

An ellipsoidal cavity model has been used to study the energy changes in occupied molecular orbitals induced by solute–solvent electrostatic interactions. Some benzene derivatives have been selected as solutes. Calculations have been carried out at the CNDO and abinitio STO-4G levels. Important variations in the molecular orbital sequence, involving a change in the HOMO nature, have been observed. A perturbation analysis is employed to understand the orbital evolution from gas phase to solution.

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