Infrared, resonance enhanced multiphoton ionization double resonance detection of energy transfer in NH3

1990 ◽  
Vol 92 (10) ◽  
pp. 5951-5958 ◽  
Author(s):  
Mary Jane Shultz ◽  
Jian Wei
1982 ◽  
Vol 86 (5-6) ◽  
pp. 445-448 ◽  
Author(s):  
Takayuki Ebata ◽  
Haruo Abe ◽  
Naohiko Mikami ◽  
Mitsuo Ito

1998 ◽  
Vol 53 (6-7) ◽  
pp. 301-304
Author(s):  
David Stephenson ◽  
John A. S. Smith

Abstract Double resonance level crossing detection cannot normally be used to record transitions between the quadrupole Zeeman levels. Neither can it be used if the quadrupole resonance frequency is larger than the proton NMR frequency in high field. A simple variation of the level crossing experiment is demonstrated which allows energy to be efficiently transferred from quadrupole to proton system and hence lead to detection in these two cases. In the case of the quadrupole Zeeman levels it allows transitions between the ±½ levels to be detected in a small magnetic field, allowing measurement of the asymmetry parameter (ƞ) for spin 3/2 systems. This is demonstrated for the 11B nucleus in triethanolamine borate. Detection of high frequency quadrupole transitions is demonstrated from which relaxation information is obtained.


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