Molecular relaxation properties studied by Rayleigh–Brillouin scattering from aqueous solutions of ammonium nitrate salts

1990 ◽  
Vol 92 (6) ◽  
pp. 3283-3291 ◽  
Author(s):  
Y. T. Lee ◽  
J. Schroeder ◽  
C. S. Choi ◽  
J. Frankel
1991 ◽  
Vol 37 (11-12) ◽  
pp. 2525-2539 ◽  
Author(s):  
C. S. Choi ◽  
J. Schroeder ◽  
Y. T. Lee ◽  
J. Frankel ◽  
J. F. Cox

1984 ◽  
Vol 49 (5) ◽  
pp. 1109-1115
Author(s):  
Jindřich Novák ◽  
Zdeněk Kodejš ◽  
Ivo Sláma

The density, viscosity, and electrical conductivity of highly concentrated solutions of ammonium nitrate in dimethyl sulphoxide have been determined over the temperature range 10-60 °C and the concentration range 7-50 mol% of the salt. The variations in the quantities as a function of temperature and concentration have been correlated by empirical equations. A comparison is made between the transport properties for the present system, aqueous solutions of ammonium nitrate, and calcium nitrate solutions in dimethyl sulphoxide.


2015 ◽  
Vol 40 (1) ◽  
Author(s):  
Manoj Kumar ◽  
Bali Ram

AbstractMeasurements on hydrodynamic and electro-osmotic permeability of water and aqueous solutions of KNO


1958 ◽  
Vol 36 (10) ◽  
pp. 1325-1331 ◽  
Author(s):  
A. N. Campbell ◽  
E. M. Kartzmark ◽  
A. G. Sherwood

Equivalent conductances, viscosities, and densities were determined for solutions equimolar in two of the three salts lithium nitrate, ammonium nitrate, and silver nitrate. The three possible combinations of two salts were each studied at 25 °C and at 35 °C.The observed conductances and viscosities were compared with those of the single salt solutions at the same total ion concentration. The conductances were lower than the mean of the conductances of the single salt solutions. The viscosities were also lower than the mean viscosities.


Author(s):  
Andrey V. Sorokin ◽  
Marina G. Kholyavka ◽  
Maria S. Lavlinskaya

The aim of this work is to synthesise chitosan and N-vinylimidazole graft-copolymers of various compositions and to study the properties of their aqueous solutions.Chitosan and N-vinylimidazole graft-copolymers were obtained by solution polymerisation in the presence of a ceric ammonium nitrate redox initiator. The synthesised graft copolymers were characterised by FTIR to determine their compositions and the grafted side chains of poly-N-vinylimidazole were characterised by gel permeation chromatography to determine their molecular wights and polydispersity indices. It was established that the obtained products are characterised by high values of yield and grafting efficiency and low values of the polydispersity index. It was found that when the content of the N-vinylimidazole links is above 57 wt%, the synthesised graft copolymers are water-soluble. Aqueous solutions of the obtained copolymers were characterised using dynamic light scattering, transmission electron microscopy, and laserDoppler microelectrophoresis. The study showed that macromolecules of graft copolymers in aqueous solutions have stimuli-sensitive properties with respect to the medium reaction and at a concentration above 10–2 wt% are characterised by a tendency to self-association forming core-crown aggregates, the geometry of which depends on the molecular masses of the grafted chains. Associates of macromolecules in solutions are characterised by positive values of the electrokinetic potential, the values of which also depend on the medium reaction. Thus, it was found that the ceric ammonium nitrate initiator allows obtaining chitosan and N-vinylimidazole graft-copolymers showing stimuli-sensitive properties in aqueous solutions and prone to self-association at concentrations above 10–2 wt%.


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