Is the counterion condensation point on polyelectrolytes a trigger of structural transition?

1988 ◽  
Vol 89 (6) ◽  
pp. 3772-3777 ◽  
Author(s):  
Gerald S. Manning
Keyword(s):  
Structural Transition ◽  
Counterion Condensation ◽  
Condensation Point

scholarly journals Mott Switching and Structural Transition in the Metal Phase of VO2 Nanodomain

2021 ◽  
Vol 3 (2) ◽  
pp. 605-610
Author(s):  
Chang-Yong Kim ◽  
Tetiana Slusar ◽  
Jinchul Cho ◽  
Hyun-Tak Kim
Keyword(s):  
Structural Transition ◽  
Metal Phase

scholarly journals Infrared phonon spectroscopy on the Cairo pentagonal antiferromagnet Bi2Fe4O9 : A study through the pressure-induced structural transition

2021 ◽  
Vol 103 (17) ◽  
Author(s):  
M. Verseils ◽  
A. P. Litvinchuk ◽  
J-B. Brubach ◽  
P. Roy ◽  
K. Beauvois ◽  
...  
Keyword(s):  
Structural Transition

Pressure-Induced Electronic and Structural Transition in Nodal-Line Semimetal ZrSiSe

2021 ◽  
Author(s):  
Enlai Dong ◽  
Ran Liu ◽  
Shifeng Niu ◽  
Xuan Luo ◽  
Kuo Hu ◽  
...  
Keyword(s):  
Structural Transition ◽  
Nodal Line

Tuning the magnetic properties of V2O3/CoFeB heterostructures across the V2O3 structural transition

2021 ◽  
Vol 5 (3) ◽  
Author(s):  
V. Polewczyk ◽  
S. K. Chaluvadi ◽  
P. Orgiani ◽  
G. Panaccione ◽  
G. Vinai ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Transition

scholarly journals UV-induced interstrand cross-linking of d(GT)n.d(CA)n is facilitated by a structural transition.

1986 ◽  
Vol 261 (22) ◽  
pp. 10051-10057
Author(s):  
J D Love ◽  
H T Nguyen ◽  
A Or ◽  
A K Attri ◽  
K W Minton
Keyword(s):  
Structural Transition ◽  
Cross Linking

scholarly journals Anion ordering enables fast H− conduction at low temperatures

2021 ◽  
Vol 7 (23) ◽  
pp. eabf7883
Author(s):  
Hiroki Ubukata ◽  
Fumitaka Takeiri ◽  
Kazuki Shitara ◽  
Cédric Tassel ◽  
Takashi Saito ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
Structural Transition ◽  
Hexagonal Lattice ◽  
Ionic Conductors ◽  
Activation Barriers ◽  
Energy Devices ◽  
Energy Applications ◽  
Chemical Disorder ◽  
New Energy

The introduction of chemical disorder by substitutional chemistry into ionic conductors is the most commonly used strategy to stabilize high-symmetric phases while maintaining ionic conductivity at lower temperatures. In recent years, hydride materials have received much attention owing to their potential for new energy applications, but there remains room for development in ionic conductivity below 300°C. Here, we show that layered anion-ordered Ba2−δH3−2δX (X = Cl, Br, and I) exhibit a remarkable conductivity, reaching 1 mS cm−1 at 200°C, with low activation barriers allowing H− conduction even at room temperature. In contrast to structurally related BaH2 (i.e., Ba2H4), the layered anion order in Ba2−δH3−2δX, along with Schottky defects, likely suppresses a structural transition, rather than the traditional chemical disorder, while retaining a highly symmetric hexagonal lattice. This discovery could open a new direction in electrochemical use of hydrogen in synthetic processes and energy devices.

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