Does reaction path curvature play a role in the diffusion theory of multidimensional activated rate processes?

Bernard J. Matkowsky; Abraham Nitzan; Zeev Schuss

doi:10.1063/1.454689

Does reaction path curvature play a role in the diffusion theory of multidimensional activated rate processes?

The Journal of Chemical Physics ◽

10.1063/1.454689 ◽

1988 ◽

Vol 88 (8) ◽

pp. 4765-4771 ◽

Cited By ~ 22

Author(s):

Bernard J. Matkowsky ◽

Abraham Nitzan ◽

Zeev Schuss

Keyword(s):

Reaction Path ◽

Diffusion Theory ◽

Rate Processes ◽

Path Curvature

Download Full-text

ChemInform Abstract: REACTION PATH CURVATURE EFFECTS IN THE ISOMERIZATION OF THE METHOXY RADICAL

Chemischer Informationsdienst ◽

10.1002/chin.198528093 ◽

1985 ◽

Vol 16 (28) ◽

Author(s):

S. M. COLWELL ◽

N. C. HANDY

Keyword(s):

Reaction Path ◽

Curvature Effects ◽

Methoxy Radical ◽

Path Curvature

Download Full-text

Effect of reaction path curvature and dimensionality on the accuracy of classical transition state theory

The Journal of Chemical Physics ◽

10.1063/1.442835 ◽

1982 ◽

Vol 76 (10) ◽

pp. 4904-4908 ◽

Cited By ~ 18

Author(s):

William H. Miller

Keyword(s):

Transition State ◽

Transition State Theory ◽

Reaction Path ◽

State Theory ◽

Classical Transition ◽

Path Curvature

Download Full-text

Test of variational transition state theory with a large‐curvature tunneling approximation against accurate quantal reaction probabilities and rate coefficients for three collinear reactions with large reaction‐path curvature: Cl+HCl, Cl+DCl, and Cl+MuCl

The Journal of Chemical Physics ◽

10.1063/1.444613 ◽

1983 ◽

Vol 78 (10) ◽

pp. 5981-5989 ◽

Cited By ~ 70

Author(s):

D. K. Bondi ◽

J. N. L. Connor ◽

Bruce C. Garrett ◽

Donald G. Truhlar

Keyword(s):

Transition State ◽

Transition State Theory ◽

Reaction Path ◽

State Theory ◽

Rate Coefficients ◽

Variational Transition State Theory ◽

Large Curvature ◽

Path Curvature ◽

Variational Transition State

Download Full-text

Reply to ‘‘Comment on the role of reaction path curvature in diffusional barrier crossing processes’’

The Journal of Chemical Physics ◽

10.1063/1.456138 ◽

1989 ◽

Vol 90 (2) ◽

pp. 1292-1293 ◽

Cited By ~ 10

Author(s):

Bernard J. Matkowsky ◽

Abraham Nitzan ◽

Zeev Schuss

Keyword(s):

Reaction Path ◽

Barrier Crossing ◽

Path Curvature ◽

Diffusional Barrier

Download Full-text

Comment on the role of reaction path curvature in diffusional barrier crossing processes

The Journal of Chemical Physics ◽

10.1063/1.456137 ◽

1989 ◽

Vol 90 (2) ◽

pp. 1291-1292 ◽

Cited By ~ 7

Author(s):

Richard S. Larson

Keyword(s):

Reaction Path ◽

Barrier Crossing ◽

Path Curvature ◽

Diffusional Barrier

Download Full-text

Improved Predictor–Corrector Integrators For Evaluating Reaction Path Curvature

Journal of Chemical Theory and Computation ◽

10.1021/ct301021y ◽

2013 ◽

Vol 9 (3) ◽

pp. 1481-1488 ◽

Cited By ~ 14

Author(s):

Hrant P. Hratchian ◽

Elfi Kraka

Keyword(s):

Reaction Path ◽

Path Curvature ◽

Predictor Corrector

Download Full-text

Tunnelling and reaction path curvature effects in the isomerization of the methoxy radical

Theoretica Chimica Acta ◽

10.1007/bf00528322 ◽

1988 ◽

Vol 74 (2) ◽

pp. 123-135 ◽

Cited By ~ 12

Author(s):

Susan M. Colwell

Keyword(s):

Reaction Path ◽

Curvature Effects ◽

Methoxy Radical ◽

Path Curvature

Download Full-text

Reaction path curvature effects in the isomerization of the methoxy radical

The Journal of Chemical Physics ◽

10.1063/1.448450 ◽

1985 ◽

Vol 82 (3) ◽

pp. 1281-1290 ◽

Cited By ~ 41

Author(s):

Susan M. Colwell ◽

Nicholas C. Handy

Keyword(s):

Reaction Path ◽

Curvature Effects ◽

Methoxy Radical ◽

Path Curvature

Download Full-text

An ab Initio Study of SN2 Reactivity at C6 in Hexopyranose Derivatives. II. Role of Populations, Barriers, and Reaction Path Curvature

The Journal of Physical Chemistry A ◽

10.1021/jp0372901 ◽

2005 ◽

Vol 109 (1) ◽

pp. 218-223 ◽

Cited By ~ 1

Author(s):

Richard Dawes ◽

Kathleen M. Gough ◽

Philip G. Hultin

Keyword(s):

Ab Initio ◽

Reaction Path ◽

Ab Initio Study ◽

Path Curvature

Download Full-text

Dynamic solvent effects on activated chemical reactions. I. Classical effects of reaction path curvature

The Journal of Chemical Physics ◽

10.1063/1.463970 ◽

1992 ◽

Vol 97 (12) ◽

pp. 9116-9137 ◽

Cited By ~ 27

Author(s):

Gregory K. Schenter ◽

Robin P. McRae ◽

Bruce C. Garrett

Keyword(s):

Chemical Reactions ◽

Solvent Effects ◽

Reaction Path ◽

Path Curvature

Download Full-text