Experimental and theoretical studies of the radiative properties of the N2+2D 1Σ+ustate

1988 ◽  
Vol 88 (12) ◽  
pp. 7501-7507 ◽  
Author(s):  
B. J. Olsson ◽  
G. Kindvall ◽  
M. Larsson
Keyword(s):  
Radiative Properties ◽  
Theoretical Studies ◽  
Experimental And Theoretical Studies

scholarly journals Multiconfiguration Dirac–Hartree–Fock radiative parameters for emission lines in Ce ii–iv ions and cerium opacity calculations for kilonovae

2020 ◽  
Vol 501 (1) ◽  
pp. 1440-1452
Author(s):  
H Carvajal Gallego ◽  
P Palmeri ◽  
P Quinet
Keyword(s):  
Neutron Star ◽  
Large Scale ◽  
Radiative Properties ◽  
Emission Lines ◽  
Atomic Data ◽  
Theoretical Studies ◽  
Electronic Correlations ◽  
Hartree Fock ◽  
Atomic Structures ◽  
Experimental And Theoretical Studies

ABSTRACT Large-scale calculations of atomic structures and radiative properties have been carried out for singly, doubly, and trebly ionized cerium. For this purpose, the purely relativistic multiconfiguration Dirac–Hartree–Fock (MCDHF) method was used, taking into account the effects of valence–valence and core–valence electronic correlations in detail. The results obtained were then used to calculate the expansion opacities characterizing the kilonovae observed as a result of neutron star mergers. Comparisons with previously published experimental and theoretical studies have shown that the results presented in this work are the most complete currently available, in terms of quantity and quality, concerning the atomic data and monochromatic opacities for Ce ii, Ce iii, and Ce iv ions.

The Stabilizing Effect of Pre-Equilibria: A Trifluoromethyl Complex as CF2 Reservoir in Catalytic Olefin Difluorocarbenation

2020 ◽  
Author(s):  
Thomas Louis-Goff ◽  
Huu Vinh Trinh ◽  
Eileen Chen ◽  
Arnold L. Rheingold ◽  
Christian Ehm ◽  
...  
Keyword(s):  
High Selectivity ◽  
Side Reactions ◽  
Theoretical Studies ◽  
Attractive Feature ◽  
Catalyst Recovery ◽  
Wide Range ◽  
Stabilizing Effect ◽  
Experimental And Theoretical Studies

A new, efficient, catalytic difluorocarbenation of olefins to give 1,1-difluorocyclopropanes is presented. The catalyst, an organobismuth complex, uses TMSCF<sub>3</sub> as a stoichiometric difluorocarbene source. We demonstrate both the viability and robustness of this reaction over a wide range of alkenes and alkynes, including electron-poor alkenes, to generate the corresponding 1,1-difluorocyclopropanes and 1,1-difluorocyclopropenes. Ease of catalyst recovery from the reaction mixture is another attractive feature of this method. In depth experimental and theoretical studies showed that the key difluorocarbene-generating step proceeds through a bismuth non-redox synchronous mechanism generating a highly reactive free CF<sub>2</sub> in an endergonic pre-equilibrium. It is the reversibility when generating the difluorocarbene that accounts for the high selectivity, while minimizing CF<sub>2</sub>-recombination side-reactions.

Strong coupling: resonant effects

2017 ◽  
Author(s):  
Alexey V. Kavokin ◽  
Jeremy J. Baumberg ◽  
Guillaume Malpuech ◽  
Fabrice P. Laussy
Keyword(s):  
Strong Coupling ◽  
Experimental Studies ◽  
Strong Coupling Regime ◽  
Theoretical Studies ◽  
Stimulated Scattering ◽  
Quantum Theories ◽  
Pump Probe ◽  
Exciton Polaritons ◽  
Linear Optical Properties ◽  
Experimental And Theoretical Studies

This chapter presents experimental studies performed on planar semiconductor microcavities in the strong-coupling regime. The first section reviews linear experiments performed in the 1990s that evidence the linear optical properties of cavity exciton-polaritons. The chapter is then focused on experimental and theoretical studies of resonantly excited microcavity emission. We mainly describe experimental configuations in which stimulated scattering was observed due to formation of a dynamical condensate of polaritons. Pump-probe and cw experiments are described in addition. Dressing of the polariton dispersion and bistability of the polariton system due to inter-condensate interactions are discussed. The semiclassical and the quantum theories of these effects are presented and their results analysed. The potential for realization of devices is also discussed.

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