Theoretical study of the time-dependent energy gap law of photoinduced charge separation reactions in solution and examination of Collins-Kimball model

1994 ◽  
Author(s):  
T. Kakitani ◽  
N. Matsuda ◽  
T. Denda ◽  
N. Mataga ◽  
Y. Enomoto
Keyword(s):  
Charge Separation ◽  
Theoretical Study ◽  
Energy Gap ◽  
Time Dependent ◽  
Energy Gap Law ◽  
Photoinduced Charge Separation ◽  
Photoinduced Charge

scholarly journals The effect of solvent relaxation time constants on free energy gap law for ultrafast charge recombination following photoinduced charge separation

2018 ◽  
Vol 17 (5) ◽  
pp. 607-616 ◽  
Author(s):  
Valentina A. Mikhailova ◽  
Roman E. Malykhin ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Charge Separation ◽  
Energy Gap ◽  
Charge Recombination ◽  
Solvent Relaxation ◽  
Equilibrium Mode ◽  
Energy Gap Law ◽  
Photoinduced Charge Separation ◽  
Relaxation Time Constants ◽  
Photoinduced Charge

Ultrafast low exergonic charge recombination following photoinduced charge separation proceeds in a non-equilibrium mode and its rate constant is nearly independent of the free energy gap.

Anionic Fluorinated Zn-porphyrin Combined with Cationic Endohedral Li-fullerene for Long-Lived Photoinduced Charge Separation with Low Energy Loss

2021 ◽  
Vol 125 (3) ◽  
pp. 918-925
Author(s):  
Kazuhira Miwa ◽  
Shinobu Aoyagi ◽  
Takahiro Sasamori ◽  
Hiroshi Ueno ◽  
Hiroshi Okada ◽  
...  
Keyword(s):  
Energy Loss ◽  
Charge Separation ◽  
Low Energy ◽  
Photoinduced Charge Separation ◽  
Photoinduced Charge

Photoinduced charge separation in microporous and mesoporous materials

2011 ◽  
Vol 89 (3) ◽  
pp. 257-265 ◽  
Author(s):  
Ranjit T. Koodali
Keyword(s):  
Mesoporous Materials ◽  
Charge Separation ◽  
Organic Molecules ◽  
Microporous Materials ◽  
Photoinduced Charge Separation ◽  
Photoinduced Charge ◽  
Mcm 41

A review of photoinduced charge separation of organic molecules in microporous and mesoporous materials is presented. In particular, the photoionization of N-alkylphenothiazine (PCn), N,N,N′,N′-tetramethylbenzidine (TMB), and porphyrin in microporous materials, such as zeolites, aluminophosphates (AlPOs), silicoaluminophosphates (SAPOs), and mesoporous materials, such as MCM-41, MCM-48, and SBA-15, is discussed.

Photoinduced charge separation in self-assembled cofacial pentamers of zinc-5,10,15,20-tetrakis(perylenediimide)porphyrin

2007 ◽  
Vol 9 (12) ◽  
pp. 1469 ◽  
Author(s):  
Michael J. Ahrens ◽  
Richard F. Kelley ◽  
Zachary E. X. Dance ◽  
Michael R. Wasielewski
Keyword(s):  
Charge Separation ◽  
Photoinduced Charge Separation ◽  
Self Assembled ◽  
Photoinduced Charge
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