Testing the Lorentz–Lorenz relation in the near‐critical binary fluid mixture isobutyric acid and water

1986 ◽  
Vol 85 (7) ◽  
pp. 3985-3991 ◽  
Author(s):  
W. V. Andrew ◽  
T. B. K. Khoo ◽  
D. T. Jacobs
Keyword(s):  
Isobutyric Acid ◽  
Fluid Mixture ◽  
Binary Fluid ◽  
Lorenz Relation

Critical consolute point in hard-sphere binary mixtures: Effect of the value of the eighth and higher virial coefficients on its location

2010 ◽  
Vol 75 (3) ◽  
pp. 359-369 ◽  
Author(s):  
Mariano López De Haro ◽  
Anatol Malijevský ◽  
Stanislav Labík
Keyword(s):  
Equation Of State ◽  
Binary Mixtures ◽  
Hard Sphere ◽  
Hard Spheres ◽  
Virial Coefficients ◽  
Fluid Mixture ◽  
Binary Fluid ◽  
Virial Series ◽  
Consolute Point ◽  
Critical Constants

Various truncations for the virial series of a binary fluid mixture of additive hard spheres are used to analyze the location of the critical consolute point of this system for different size asymmetries. The effect of uncertainties in the values of the eighth virial coefficients on the resulting critical constants is assessed. It is also shown that a replacement of the exact virial coefficients in lieu of the corresponding coefficients in the virial expansion of the analytical Boublík–Mansoori–Carnahan–Starling–Leland equation of state, which still leads to an analytical equation of state, may lead to a critical consolute point in the system.

scholarly journals Phase behavior of a symmetrical binary fluid mixture

2006 ◽  
Vol 125 (23) ◽  
pp. 234503 ◽  
Author(s):  
Jürgen Köfinger ◽  
Nigel B. Wilding ◽  
Gerhard Kahl
Keyword(s):  
Phase Behavior ◽  
Fluid Mixture ◽  
Binary Fluid

scholarly journals Drag Coefficient of a Rigid Spherical Particle in a Near-Critical Binary Fluid Mixture

2013 ◽  
Vol 82 (8) ◽  
pp. 084003 ◽  
Author(s):  
Ryuichi Okamoto ◽  
Youhei Fujitani ◽  
Shigeyuki Komura
Keyword(s):  
Drag Coefficient ◽  
Spherical Particle ◽  
Fluid Mixture ◽  
Binary Fluid

scholarly journals Nonreciprocity as a generic route to traveling states

2020 ◽  
Vol 117 (33) ◽  
pp. 19767-19772 ◽  
Author(s):  
Zhihong You ◽  
Aparna Baskaran ◽  
M. Cristina Marchetti
Keyword(s):  
Time Reversal ◽  
Reaction Diffusion ◽  
Parameter Tuning ◽  
Critical Value ◽  
Fluid Mixture ◽  
Effective Interactions ◽  
Finite Velocity ◽  
Binary Fluid ◽  
Static Pattern ◽  
Antagonistic Interactions

We examine a nonreciprocally coupled dynamical model of a mixture of two diffusing species. We demonstrate that nonreciprocity, which is encoded in the model via antagonistic cross-diffusivities, provides a generic mechanism for the emergence of traveling patterns in purely diffusive systems with conservative dynamics. In the absence of nonreciprocity, the binary fluid mixture undergoes a phase transition from a homogeneous mixed state to a demixed state with spatially separated regions rich in one of the two components. Above a critical value of the parameter tuning nonreciprocity, the static demixed pattern acquires a finite velocity, resulting in a state that breaks both spatial and time-reversal symmetry, as well as the reflection parity of the static pattern. We elucidate the generic nature of the transition to traveling patterns using a minimal model that can be studied analytically. Our work has direct relevance to nonequilibrium assembly in mixtures of chemically interacting colloids that are known to exhibit nonreciprocal effective interactions, as well as to mixtures of active and passive agents where traveling states of the type predicted here have been observed in simulations. It also provides insight on transitions to traveling and oscillatory states seen in a broad range of nonreciprocal systems with nonconservative dynamics, from reaction–diffusion and prey–predators models to multispecies mixtures of microorganisms with antagonistic interactions.

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