Erratum: Magnetic susceptibility of Nd(BrO3)3 ⋅ 9H2O single crystal: Effects of the crystal field and calculation of the electrostatic crystal field parameters [J. Chem. Phys. 80, 3753 (1984)]

1986 ◽  
Vol 84 (4) ◽  
pp. 2433-2433 ◽  
Author(s):  
D. Neogy ◽  
A. Chatterji ◽  
T. Purohit
Keyword(s):  
Magnetic Susceptibility ◽  
Single Crystal ◽  
Crystal Field ◽  
Chem Phys ◽  
Crystal Field Parameters

1,3,4-Thiadiazole-2,5-dithiol as a complexing agent. Complexes of RuIII, RuII, RhIII, PdIV IrIII and PtIV

1975 ◽  
Vol 28 (4) ◽  
pp. 763 ◽  
Author(s):  
MR Gajendragad ◽  
U Agarwala
Keyword(s):  
Magnetic Susceptibility ◽  
Metal Ions ◽  
Spectral Data ◽  
Crystal Field ◽  
Complexing Agent ◽  
Chemical Analyses ◽  
Infrared Spectral ◽  
Crystal Field Parameters

Complexes of RuIII, RuII, RhIII, PdIV, IrIII and PtIV with 1,3,4-thiadiazole- 2,5-dithiol have been prepared. Probable structures for the complexes have been proposed on the basis of chemical analyses, magnetic susceptibility and electronic and infrared spectral data. Crystal field parameters have been calculated which are in accordance with the structures proposed. In every complex the ligand behaves as a unidentate towards two metal ions.

scholarly journals EPR of Gd3+ in a Single Crystal of Thorium disulfide (ThS2)

1981 ◽  
Vol 36 (11) ◽  
pp. 1163-1168
Author(s):  
G. Amoretti ◽  
D. C. Giori ◽  
V. Varacca
Keyword(s):  
Single Crystal ◽  
Crystal Field ◽  
Site Symmetry ◽  
Spin Hamiltonian ◽  
Fitting Procedure ◽  
Numerical Fitting ◽  
Crystal Field Symmetry ◽  
Field Symmetry ◽  
Crystal Field Parameters ◽  
Low Symmetry

In this paper we report the experimental angular behaviour of the EPR spectra for a single crystal of Thorium disulfide (ThS2) doped with Gd3+ at very low concentration (of the order of 10 p.p.m.). The experimental data are interpreted in terms of a spin Hamiltonian which reflects the crystal field symmetry at the Th site, that is monoclinic Cs, and therefore shows that the doping ions enter substitutionally without lowering the site symmetry. The low symmetry and the unusually large values of the crystal field parameters b20 and b22 have made it necessary to use a numerical fitting procedure, starting from the exact numerical diagonalization of the energy matrix for any given direction of the static magnetic field.

Magnetic susceptibility and crystal field parameters of ytterbium sesquiselenide

1980 ◽  
Vol 34 (3) ◽  
pp. 195-197 ◽  
Author(s):  
L. Pawlak ◽  
M. Duczmal ◽  
S. Pokrzywnicki ◽  
A. Czopnik
Keyword(s):  
Magnetic Susceptibility ◽  
Crystal Field ◽  
Crystal Field Parameters

Further studies of the enhanced nuclear magnet TmPO 4

1989 ◽  
Vol 424 (1867) ◽  
pp. 245-254 ◽  
Keyword(s):  
Magnetic Resonance ◽  
Crystal Field ◽  
Lattice Relaxation ◽  
Zeeman Splitting ◽  
Chem Phys ◽  
Spin Lattice Relaxation ◽  
Relaxation Rates ◽  
Spin Lattice ◽  
Crystal Field Parameters ◽  
T Values

In thulium phosphate, TmPO 4 , the lowest levels of the manifold 3 H 6 , split by the crystal field, are a singlet, and a doublet, followed by another singlet. Measurements by Bleaney et al . ( Proc. R. Soc. Lond. A 387, 75(1983)) of enhanced nuclear magnetic resonance were fitted to these levels by using a set of crystal-field parameters and wave functions based on optical absorption measurements of Brecher et al . ( J. chem. Phys. 49, 3303 (1968)) on Eu 3+ in YPO 4 . Two other sets of parameters (Hodges: J. Phys. 44, 833 (1983); Becker et al.: J. chem. Phys. 81, 2872 (1984)) give similar levels, except that the two lowest singlets are interchanged. A fresh set of parameters (adjusted from those of Hodges) is shown to give the correct Zeeman splitting for the doublet, and to fit the enhanced nuclear resonance measurements. Measurements of phonon velocities and of acoustic magnetic resonance at 0.7 GHz are also reported at field strengths up to 3 T. Values of the direct spin-lattice relaxation rates derived from these measurements are compared with results from other methods. The Orbach-Aminov relaxation rate is discussed, together with that in some other enhanced nuclear paramagnets.

scholarly journals Optical spectra, crystal-field parameters, and magnetic susceptibility of multiferroicNdFe3(BO3)4

2007 ◽  
Vol 75 (22) ◽  
Author(s):  
M. N. Popova ◽  
E. P. Chukalina ◽  
T. N. Stanislavchuk ◽  
B. Z. Malkin ◽  
A. R. Zakirov ◽  
...  
Keyword(s):  
Magnetic Susceptibility ◽  
Crystal Field ◽  
Optical Spectra ◽  
Crystal Field Parameters

The magnetic susceptibility of an MnO single crystal

1959 ◽  
Vol 20 (2-3) ◽  
pp. 424-426 ◽  
Author(s):  
T.R. McGuire ◽  
R.J. Happel
Keyword(s):  
Magnetic Susceptibility ◽  
Single Crystal
Sign in / Sign up

Export Citation Format

Share Document