Charge–transfer organic crystals: Molecular vibrations and spectroscopic effects of electron–molecular vibration coupling of the strong electron acceptor TCNQF4

1986 ◽  
Vol 84 (8) ◽  
pp. 4149-4162 ◽  
Author(s):  
Moreno Meneghetti ◽  
Cesare Pecile
Keyword(s):  
Charge Transfer ◽  
Electron Acceptor ◽  
Molecular Vibration ◽  
Organic Crystals ◽  
Molecular Vibrations ◽  
Strong Electron ◽  
Vibration Coupling

Electron–Intramolecular Vibration Coupling in Charge-Transfer Salts Studied by Infrared Spectroscopy

1998 ◽  
Vol 12 (16n17) ◽  
pp. 1643-1672 ◽  
Author(s):  
V. M. Yartsev ◽  
A. Graja
Keyword(s):  
Optical Properties ◽  
Infrared Spectroscopy ◽  
Charge Transfer ◽  
Theoretical Calculations ◽  
Molecular Crystals ◽  
Molecular Vibration ◽  
Short Discussion ◽  
Intramolecular Vibration ◽  
Charge Transfer Salts ◽  
Vibration Coupling

A short discussion of theoretical calculations of the optical properties of quasi-one and quasi-bidimensional molecular crystals is presented. Special attention is devoted to the electron–molecular vibration coupling which is analyzed in charge-transfer salts with tetrathiafulvalene (TTF) derivatives (including giant analoges of TTF) as donor components.

How active sites facilitate charge-transfer interactions of silver and gold clusters with TCNQ?

2017 ◽  
Vol 19 (32) ◽  
pp. 21777-21782 ◽  
Author(s):  
Jing Chen ◽  
Zhixun Luo ◽  
Jiannian Yao
Keyword(s):  
Charge Transfer ◽  
Noble Metal ◽  
Electron Acceptor ◽  
Active Sites ◽  
Organic Molecules ◽  
Metal Clusters ◽  
Gold Clusters ◽  
Acceptor Molecule ◽  
Strong Electron

Utilizing a strong electron acceptor molecule tetracyanoquinodimethane (TCNQ) as probe, we demonstrate how the electronic features and geometric sites determine charge-transfer interactions of noble metal clusters with organic molecules.

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