Supercritical fluid phase separations: Implications for detonation properties of condensed explosives

1986 ◽  
Vol 84 (10) ◽  
pp. 5845-5856 ◽  
Author(s):  
Francis H. Ree
Keyword(s):  
Supercritical Fluid ◽  
Fluid Phase ◽  
Detonation Properties ◽  
Phase Separations ◽  
Condensed Explosives

scholarly journals Supercritical Fluid Phase Separations Induced by Chemical Reactions

1997 ◽  
Vol 499 ◽  
Author(s):  
Francis H. Ree ◽  
James A. Viecelli
Keyword(s):  
High Pressure ◽  
Phase Separation ◽  
Supercritical Fluid ◽  
Chemical Reactions ◽  
Fluid Phase ◽  
Reactive System ◽  
Phase Separations ◽  
Rich Phase ◽  
Statistical Mechanical ◽  
Mechanical Studies

ABSTRACTStatistical mechanical studies predict that a chemically reactive system containing species composed of C, H, N, O atoms can exhibit a phase separation into a N2-rich and a N2-poor phase. The present work is concerned with the effect of the fluid phase separation upon addition of F atoms to the system. Our study shows that F atoms mainly appear as a constituent of HF in a N2-poor fluid phase up to a certain pressure beyond which they occur as CF4 in a N2-rich phase and that the phase separation may be abrupt in a thermodynamic sense. The pressure at the phase boundary can occur at about 30 GPa at 3000 K and about 10 GPa to 20 GPa at 1000 K. Some of these ranges may be accessible by present-day experimental high-pressure techniques. We discuss implications of this study to detonation physics.

Fabrication of fluorographene nanosheets with high yield and good quality based on supercritical fluid-phase exfoliation

2016 ◽  
Vol 18 (7) ◽  
Author(s):  
Qi Chen ◽  
Yan Ji ◽  
Danying Zhang ◽  
Jia Shi ◽  
Yinghong Xiao ◽  
...  
Keyword(s):  
Supercritical Fluid ◽  
Fluid Phase ◽  
High Yield

Solid-supercritical fluid phase equilibria

1989 ◽  
Vol 61 (6) ◽  
pp. 1065-1074 ◽  
Author(s):  
B. C.-Y. Lu ◽  
D. Zhang
Keyword(s):  
Phase Equilibria ◽  
Supercritical Fluid ◽  
Fluid Phase ◽  
Fluid Phase Equilibria
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