Effect of pressure on rotational isomerism of chloroacetone in carbon disulfide

Yoshihiro Taniguchi; Seiji Sawamura; Isao Murakoshi

doi:10.1063/1.449322

Effect of pressure on rotational isomerism of chloroacetone in carbon disulfide

The Journal of Chemical Physics ◽

10.1063/1.449322 ◽

1985 ◽

Vol 83 (5) ◽

pp. 2305-2310 ◽

Cited By ~ 7

Author(s):

Yoshihiro Taniguchi ◽

Seiji Sawamura ◽

Isao Murakoshi

Keyword(s):

Carbon Disulfide ◽

Rotational Isomerism ◽

Effect Of Pressure

Download Full-text

Effect of pressure on the internal rotation angle of biphenyl in carbon disulfide

The Journal of Chemical Physics ◽

10.1063/1.455593 ◽

1988 ◽

Vol 89 (9) ◽

pp. 5417-5421 ◽

Cited By ~ 19

Author(s):

Minoru Katō ◽

Mikio Higashi ◽

Yoshihiro Taniguchi

Keyword(s):

Internal Rotation ◽

Carbon Disulfide ◽

Rotation Angle ◽

Effect Of Pressure ◽

Internal Rotation Angle

Download Full-text

The Effect of Pressure on Self‐Diffusion in Carbon Disulfide

The Journal of Chemical Physics ◽

10.1063/1.1698872 ◽

1953 ◽

Vol 21 (2) ◽

pp. 267-273 ◽

Cited By ~ 30

Author(s):

R. C. Koeller ◽

H. G. Drickamer

Keyword(s):

Carbon Disulfide ◽

Effect Of Pressure ◽

Self Diffusion

Download Full-text

Proton Magnetic Resonance Studies of Rotational Isomerism in Halotoluene Derivatives. IX. Rotational Barriers and Conformational Energy Differences in α,α,α′,α′,α″,α″, 2,4,6-Nonachloromesitylene

Canadian Journal of Chemistry ◽

10.1139/v73-317 ◽

1973 ◽

Vol 51 (13) ◽

pp. 2110-2117 ◽

Cited By ~ 6

Author(s):

J. Peeling ◽

B. W. Goodwin ◽

T. Schaefer ◽

J. B. Rowbotham

Keyword(s):

Magnetic Resonance ◽

Carbon Disulfide ◽

Proton Magnetic Resonance ◽

Methylene Chloride ◽

Activation Parameters ◽

Rotational Isomerism ◽

Conformational Energy ◽

The Other ◽

Free Energies ◽

Magnetic Resonance Studies

The activation parameters for the rotation of the dichloromethyl groups in the two conformations of α,α,α′,α′,α″,α″,2,4,6-nonachloromesitylene are reported for solutions in toluene-d8 and in methylene chloride. In addition, free energies of activation are given for solutions in bromochloromethane, tri-chloroethylene, and in carbon disulfide. The free energies of activation are lower in the toluene solution than in the other solutions. The entropies of activation are near zero, perhaps slightly negative. The symmetrical conformation is more stable than the unsymmetrical one in all the solvents.

Download Full-text