scholarly journals Comment on: Corrected Debye–Hückel theory of electrolyte solutions [J. Chem. Phys. 78, 5759 (1983)]

1984 ◽  
Vol 80 (6) ◽  
pp. 2985-2985 ◽  
Author(s):  
C. W. Outhwaite
Keyword(s):  
Electrolyte Solutions ◽  
Chem Phys ◽  
Hückel Theory

scholarly journals The Debye-Hückel theory and its importance in modeling electrolyte solutions

2018 ◽  
Vol 462 ◽  
pp. 130-152 ◽  
Author(s):  
Georgios M. Kontogeorgis ◽  
Bjørn Maribo-Mogensen ◽  
Kaj Thomsen
Keyword(s):  
Electrolyte Solutions ◽  
Hückel Theory

scholarly journals Comment on “Water-water correlations in electrolyte solutions probed by hyper-Rayleigh scattering” [J. Chem. Phys. 147, 214505 (2017)]

2018 ◽  
Vol 149 (16) ◽  
pp. 167101 ◽  
Author(s):  
Y. Chen ◽  
H. I. Okur ◽  
N. Dupertuis ◽  
J. Dedic ◽  
D. M. Wilkins ◽  
...  
Keyword(s):  
Rayleigh Scattering ◽  
Electrolyte Solutions ◽  
Chem Phys

A lattice model of electrolytes for the whole concentration range

1987 ◽  
Vol 52 (7) ◽  
pp. 1672-1679 ◽  
Author(s):  
Ivan Horsák ◽  
Ivo Sláma
Keyword(s):  
Experimental Data ◽  
Simple Model ◽  
Infinite Dilution ◽  
Regular Solution Model ◽  
Electrolyte Solutions ◽  
Strong Electrolyte ◽  
Hückel Theory ◽  
Proposed Model ◽  
Pure Solvent ◽  
Pure Salt

Based on the quasi-lattice concept, a simple model is proposed for calculating the quantities of mixing of strong electrolyte solutions over the whole concentration range from pure solvent to pure salt. This model is analogous to the regular solution model for non-electrolyte systems. Relationships for the activity coefficients of the solvent and salt have been derived, and the behaviour of the model in the limit of infinite dilution is discussed by comparison with the Debye-Huckel theory. The adequacy of equations derived from the proposed model has been tested by fitting published experimental data for the activities of water in the systems (Li, K)NO3-H2O and (Ag, Tl)NO3-H2O, which have been measured over the whole concentration range.

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