Electric‐dipole moment of CaF (X 2Σ+) by molecular beam, laser‐rf, double‐resonance study of Stark splittings

1984 ◽  
Vol 80 (6) ◽  
pp. 2283-2287 ◽  
Author(s):  
W. J. Childs ◽  
L. S. Goodman ◽  
U. Nielsen ◽  
V. Pfeufer
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Molecular Beam ◽  
Double Resonance ◽  
Beam Laser

Molekülstrahl-Resonanz-Messungen von Hyperfeinstruktur, Zeeman-und Stark-Effekt an TlCl-Isotopen in verschiedenen Schwingungszuständen / Molecular Beam Resonance Measurements of Hyperfine Structure, Zeeman- and Stark-Effect of TICl-lsotopes in Different Vibrational States

1972 ◽  
Vol 27 (1) ◽  
pp. 77-91 ◽  
Author(s):  
R. Ley ◽  
W. Schauer
Keyword(s):  
Magnetic Field ◽  
Dipole Moment ◽  
Hyperfine Structure ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Molecular Beam ◽  
Stark Effect ◽  
Zeeman Effect ◽  
Magnetic Shielding ◽  
Vibrational States

AbstractHyperfine structure, Stark effect and Zeeman effect of the TlCl molecule have been measured with a molecular beam apparatus using electric four poles as deflecting fields and a homogeneous electric field parallel to a superimposed magnetic field in the transition region. Electric dipole transitions were induced between the hyperfine structure levels of the first rotational state J = 1 in both strong and weak external field.The following quantities could be evaluated from the spectra: the electric dipole moment µel and the magnetic rotational dipole moment µJ of the molecule, the nuclear spin-rotational interactions c1 and c2, the scalar and tensor part of the nuclear dipole-dipole interaction dS and dT, the quadrupole coupling constant e q Q of the Cl nucleus, the anisotropy of the magnetic susceptibility ξ⊥− ξ∥ , the anisotropy of the magnetic shielding of the external magnetic field at the position of both nuclei (σ⊥- σ∥)1 and (σ⊥- σ∥)2, the magnetic moment of the Cl nucleus multiplied by the scalar part of the magnetic shielding tensor µ2 · (1 - σS)2. For the most abundant isotop 205Tl35Cl the vibrational dependence of most of these quantities was measured in the vibrational states v =0, 1, 2, 3. Isotopic effects for 203Tl35Cl, 205Tl37Cl and 203Tl37Cl were investigated in the ground vibrational state. In addition the vibrational dependence of the electric dipole moment was measured for all isotopic species.It is pointed out that the usual connections between (σ⊥- σ∥)1,2 and c1,2 and between ξ⊥− ξ∥ and µJ do not hold when the excited electronic states of the molecule obey Hund’s coupling case c, which occurs most probably in TlCl.

ROTATIONAL SPECTRA OF RbF BY THE ELECTRIC RESONANCE METHOD

1958 ◽  
Vol 36 (2) ◽  
pp. 171-183 ◽  
Author(s):  
H. Lew ◽  
D. Morris ◽  
F. E. Geiger Jr. ◽  
J. T. Eisinger
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Internuclear Distance ◽  
Electric Dipole ◽  
Molecular Beam ◽  
Resonance Method ◽  
Mass Ratio ◽  
Electric Resonance ◽  
Rotational States ◽  
Rotational Spectra

Transitions between the J = 0 and J = 1 rotational states of RbF have been measured by means of the molecular beam electric resonance method. The following rotational constants have been determined (all frequencies in Mc./sec):[Formula: see text]The quadrupole interaction constants −eqQ/h in the J = 1 state are found to be[Formula: see text]The equilibrium internuclear distance is re = (2.26554 ± 0.00005) × 10−8 cm. The electric dipole moment of Rb85F in the ν = 0 state is μ = (8.80 ± 0.10) × 10−18 e.s.u. The mass ratio of the Rb isotopes is M85/M87 = 0.9770148 ± 0.0000052.

ROTATIONAL SPECTRUM OF K39F BY THE MOLECULAR BEAM ELECTRIC RESONANCE METHOD

1960 ◽  
Vol 38 (3) ◽  
pp. 482-494 ◽  
Author(s):  
G. W. Green ◽  
H. Lew
Keyword(s):  
Dipole Moment ◽  
Quadrupole Interaction ◽  
Electric Dipole Moment ◽  
Internuclear Distance ◽  
Electric Dipole ◽  
Molecular Beam ◽  
Resonance Method ◽  
Rotational Spectrum ◽  
Electric Resonance ◽  
Rotational States

Transitions between the J = 0 and J = 1 rotational states of K39F have been measured by means of the molecular beam electric resonance method. The following rotational constants have been determined (all frequencies in Mc/sec):[Formula: see text]The quadrupole interaction constants eqQ as measured in the J = 1 state are found to be[Formula: see text]The equilibrium internuclear distance obtained directly from Be is[Formula: see text]The electric dipole moment in the ν = 0 state is[Formula: see text]

ROTATIONAL CONSTANTS AND ELECTRIC DIPOLE MOMENT OF NaF

1963 ◽  
Vol 41 (9) ◽  
pp. 1461-1469 ◽  
Author(s):  
R. K. Bauer ◽  
H. Lew
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Molecular Beam ◽  
Resonance Method ◽  
Interaction Constant ◽  
Spin Rotation ◽  
Vibrational States ◽  
Electric Resonance ◽  
Rotational Constants

Transitions between the J = 0 and J = 1 rotational levels of Na23F19 have been measured by the molecular beam electric resonance method in the three lowest vibrational states. The following rotational constants have been determined (all frequencies in Mc/sec):[Formula: see text]The Na quadrupole interaction constants in the J = 1 level are:[Formula: see text]The spin-rotation interaction constant for Na in the J = 1 level for ν = 0, 1, and 2 is[Formula: see text]The equilibrium internuclear distance computed directly from Be is[Formula: see text]The electric dipole moment is:[Formula: see text]

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