2H NMR line shapes and molecular motion in solid charge‐transfer complexes

1982 ◽  
Vol 77 (2) ◽  
pp. 1069-1070 ◽  
Author(s):  
J. A. Ripmeester
Keyword(s):  
Charge Transfer ◽  
Molecular Motion ◽  
Charge Transfer Complexes ◽  
2H Nmr ◽  
Line Shapes

MOLECULAR MOTION IN WEAK CHARGE TRANSFER COMPLEXES

1966 ◽  
Vol 44 (8) ◽  
pp. 945-952 ◽  
Author(s):  
D. F. R. Gilson ◽  
C. A. McDowell
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Charge Transfer ◽  
Molecular Motion ◽  
Charge Transfer Complexes ◽  
Weak Charge ◽  
Magnetic Resonance Studies ◽  
Second Moments ◽  
Line Nuclear Magnetic Resonance ◽  
Pure Compounds ◽  
Wide Line

"Wide line" nuclear magnetic resonance studies of several charge transfer complexes are reported. Line width transitions and comparisons of theoretical and experimental second moments indicate that molecular rotation occurs in several of these complexes. Estimates of the barriers to reorientation in the complexes show these to be lower than those observed for the corresponding pure compounds.

Modulations in line shapes of magnetoconductance curves for diodes of pentacene:fullerene charge transfer complexes

2014 ◽  
Vol 15 (11) ◽  
pp. 3076-3081 ◽  
Author(s):  
Wei-Shun Huang ◽  
Zhe-Rui Xu ◽  
Kuo-Cheng Chen ◽  
Tzung-Fang Guo ◽  
J.C.A. Huang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Line Shapes

Magnetic properties of new charge-transfer complexes based on manganese porphyrins

1997 ◽  
Vol 90 (3) ◽  
pp. 407-413
Author(s):  
MARC KELEMEN ◽  
CHRISTOPH WACHTER ◽  
HUBERT WINTER ◽  
ELMAR DORMANN ◽  
RUDOLF GOMPPER ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Manganese Porphyrins

Charge Transfer Complexation Boosts Molecular Conductance Through Fermi Level Pinning

2018 ◽  
Author(s):  
Kun Wang ◽  
Andrea Vezzoli ◽  
Iain Grace ◽  
Maeve McLaughlin ◽  
Richard Nichols ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Single Molecule ◽  
Quantum Interference ◽  
Transmission Function ◽  
Scanning Tunneling ◽  
Charge Transfer Complexes ◽  
Tunneling Microscopy ◽  
Quantum Interference Effect ◽  
Single Molecule Junctions ◽  
Charge Transfer Complexation

We have used scanning tunneling microscopy to create and study single molecule junctions with thioether-terminated oligothiophene molecules. We find that the conductance of these junctions increases upon formation of charge transfer complexes of the molecules with tetracyanoethene, and that the extent of the conductance increase is greater the longer is the oligothiophene, i.e. the lower is the conductance of the uncomplexed molecule in the junction. We use non-equilibrium Green's function transport calculations to explore the reasons for this theoretically, and find that new resonances appear in the transmission function, pinned close to the Fermi energy of the contacts, as a consequence of the charge transfer interaction. This is an example of a room temperature quantum interference effect, which in this case boosts junction conductance in contrast to earlier observations of QI that result in diminished conductance.<br>

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