Equilibrium properties of hard‐sphere fluid mixture in the semiclassical limit

1982 ◽  
Vol 77 (11) ◽  
pp. 5784-5793 ◽  
Author(s):  
U. N. Singh ◽  
S. K. Sinha
Keyword(s):  
Hard Sphere ◽  
Semiclassical Limit ◽  
Fluid Mixture ◽  
Hard Sphere Fluid

The structure of a hard sphere fluid mixture confined to a slit

1989 ◽  
Vol 66 (1) ◽  
pp. 143-160 ◽  
Author(s):  
M. Moradi ◽  
G. Rickayzen
Keyword(s):  
Hard Sphere ◽  
Fluid Mixture ◽  
Hard Sphere Fluid

Critical consolute point in hard-sphere binary mixtures: Effect of the value of the eighth and higher virial coefficients on its location

2010 ◽  
Vol 75 (3) ◽  
pp. 359-369 ◽  
Author(s):  
Mariano López De Haro ◽  
Anatol Malijevský ◽  
Stanislav Labík
Keyword(s):  
Equation Of State ◽  
Binary Mixtures ◽  
Hard Sphere ◽  
Hard Spheres ◽  
Virial Coefficients ◽  
Fluid Mixture ◽  
Binary Fluid ◽  
Virial Series ◽  
Consolute Point ◽  
Critical Constants

Various truncations for the virial series of a binary fluid mixture of additive hard spheres are used to analyze the location of the critical consolute point of this system for different size asymmetries. The effect of uncertainties in the values of the eighth virial coefficients on the resulting critical constants is assessed. It is also shown that a replacement of the exact virial coefficients in lieu of the corresponding coefficients in the virial expansion of the analytical Boublík–Mansoori–Carnahan–Starling–Leland equation of state, which still leads to an analytical equation of state, may lead to a critical consolute point in the system.

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