Mobilities and longitudinal diffusion coefficients for Li+ ions in Ar, Kr, and Xe at room temperature

1982 ◽  
Vol 76 (5) ◽  
pp. 2672-2674 ◽  
Author(s):  
M. Takebe ◽  
Y. Satoh ◽  
K. Iinuma ◽  
K. Seto
Keyword(s):  
Diffusion Coefficients ◽  
Room Temperature ◽  
Longitudinal Diffusion

Measurement of the diffusion coefficients of reactive species in dilute gases

1982 ◽  
Vol 380 (1779) ◽  
pp. 241-258 ◽  
Keyword(s):  
Gas Phase ◽  
Diffusion Coefficients ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Reactive Species ◽  
Resonance Fluorescence ◽  
Hydrogen Atoms ◽  
Chromatographic Effect ◽  
Diffusion Of Hydrogen

A technique has been developed for measuring the diffusion coefficients of atoms and other reactive species in gases below atmospheric pressure. The technique consists of measuring the rate of dispersion of a pulse of reactive species in a stream of gas flowing rapidly ( ca . 10 m s -1 ) down a quartz tube. The reactive species are observed and the profile of the pulses measured by using resonance fluorescence. The technique has been used at room temperature, but in principle measurements could be made at elevated temperatures. Measurements have been made of the rates of diffusion of hydrogen atoms in argon and nitrogen, and values for the diffusion coefficients of 1.61 ± 0.04 and 1.35 ± 0.03 cm 2 s -1 respectively, at 1 atmosphere ( ca . 10 5 Pa) and 294 K, have been obtained. Incidentally to the primary purpose of the experiment, it was observed that the hydrogen atoms spend a small fraction of their time of passage along the tube reversibly adsorbed on its walls. From the measurements, both the partition coefficient, giving the ratio of hydrogen atoms on the walls to those in the gas phase, and the rates of adsorption and desorp­tion can be obtained. This appears to be the first observation of a chromatographic effect for a highly reactive species.

Temperature Dependence of the Diffusion of 1,2-Dichloroethane, 1,1,1-Trichloroethane, Trichloroethylene, and Tetrachloroethylene in Air

1971 ◽  
Vol 49 (11) ◽  
pp. 1965-1967 ◽  
Author(s):  
Harry Watts
Keyword(s):  
Temperature Dependence ◽  
Diffusion Coefficients ◽  
Room Temperature ◽  
Evaporation Method ◽  
Temperature Range ◽  
Boiling Points ◽  
Rate Of Evaporation

The diffusion coefficients in air of 1,1-dichloroethane, 1,1,1-trichloroethane, trichloroethylene, and tetrachloroethylene have been measured over a temperature range from room temperature to close to their boiling points by a rate of evaporation method.

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