Shape resonance effects in the photoabsorption spectra of BF3

1981 ◽  
Vol 75 (2) ◽  
pp. 619-624 ◽  
Author(s):  
John R. Swanson ◽  
Dan Dill ◽  
J. L. Dehmer
Keyword(s):  
Shape Resonance ◽  
Resonance Effects

Broad shape resonance effects in CaF Rydberg states

2006 ◽  
Vol 124 (19) ◽  
pp. 194302 ◽  
Author(s):  
Serhan N. Altunata ◽  
Stephen L. Coy ◽  
Robert W. Field
Keyword(s):  
Rydberg States ◽  
Shape Resonance ◽  
Resonance Effects

scholarly journals Shape resonance effects in the rotationally resolved photoelectron spectra of O2

1990 ◽  
Vol 93 (7) ◽  
pp. 5345-5346 ◽  
Author(s):  
M. Braunstein ◽  
V. McKoy ◽  
S. N. Dixit ◽  
R. G. Tonkyn ◽  
M. G. White
Keyword(s):  
Photoelectron Spectra ◽  
Shape Resonance ◽  
Resonance Effects

A New Type of Precision Tire

1988 ◽  
Vol 16 (4) ◽  
pp. 200-207
Author(s):  
O. B. Tretyakov
Keyword(s):  
Stress Concentration ◽  
Failure Rates ◽  
Stress Strain ◽  
Radial Tire ◽  
Resonance Effects ◽  
Precision Stage ◽  
New Type ◽  
Degree Of Order

Abstract A process is suggested for improving the rubber-cord composite in a radial tire through precision stage-by-stage molding of its parts. This starts by casting an inner elastomeric envelope of the carcass from a liquid oligomer mix. The full molding technology uses acoustic and resonance effects to optimize the degree of order of the structure and of rubber uniformity. The resultant precision tires should have a higher degree of order of both macro- and microstructure than do present commercial tires. Reduced stress concentration in locations that have high failure rates in commercial tires are considered. A new theory, CSSOT, is used for optimizing tires from results of stress-strain cycles.

Estimate of Hyperconjugation Strength in Alkylaromatics and Unsaturated Hydrocarbons Derived from Refractometric Data

2020 ◽  
Vol 23 (23) ◽  
pp. 2598-2613
Author(s):  
Boris A. Zaitsev
Keyword(s):  
Quantitative Estimation ◽  
Physical Phenomenon ◽  
Unsaturated Hydrocarbons ◽  
Resonance Effects ◽  
Alkyl Derivatives ◽  
Retrospective View ◽  
Scientific Papers ◽  
Polycyclic Aromatic ◽  
Qualitative Measure ◽  
Steric Inhibition Of Resonance

: A retrospective view of exaltation of refraction observed for many unsaturated and aromatic compounds demonstrates that this physical phenomenon is undeservedly considered only as a qualitative measure of conjugation. This mini-review discusses numerous papers by the author that have been published earlier in inaccessible periodicals and collections of scientific papers. Using a great number of illustrations, the author shows that this parameter can be successfully used for quantitative estimate of resonance effects in organic and polymer chemistry. The methods for derivation of strictly additive atomic and group refraction constants are described; these constants were subsequently used as a tool that allowed quantitative estimation of resonance effects in mono-, di-, tri- and polyalkylbenzenes, alkylnaphthalenes, some alkyl derivatives of unsaturated hydrocarbons. These effects cause strictly fixed increase in refraction of carbon atoms in different structural modifications (graphene, fullerene, diamond) and in polycyclic aromatic hydrocarbons. The relevant results regarding quantitative estimation of degree of steric inhibition of resonance in sterically hindered ortho-dialkylbenzenes, 1,2,3- trialkyl-, 1,2,3,4-tetraalkyl-, and 1,2,3,4,5-polyalkylbenzenes accumulated by the author are summarized.

Kinetic study of hydrolysis of benzoates. part xxvii. ortho substituent effect in alkaline hydrolysis of phenyl esters of substituted benzoic acids in aqueous Bu4NBr

2009 ◽  
Vol 74 (1) ◽  
pp. 29-42 ◽  
Author(s):  
Vilve Nummert ◽  
Mare Piirsalu ◽  
Signe Vahur ◽  
Oksana Travnikova ◽  
Ilmar A. Koppel
Keyword(s):  
Alkaline Hydrolysis ◽  
Rate Constants ◽  
Pure Water ◽  
Substituent Effects ◽  
Benzoic Acids ◽  
Resonance Effects ◽  
The Media ◽  
Substituted Benzoic Acids ◽  
Hydrolysis Of ◽  
Ortho Substituent

The second-order rate constants k (in dm3 mol–1 s–1) for alkaline hydrolysis of phenyl esters of meta-, para- and ortho-substituted benzoic acids, X-C6H4CO2C6H5, have been measured spectrophotometrically in aqueous 0.5 and 2.25 M Bu4NBr at 25 °C. The substituent effects for para and meta derivatives were described using the Hammett relationship. For the ortho derivatives the Charton equation was used. For ortho-substituted esters two steric scales were involved: the EsB and the Charton steric (υ) constants. When going from pure water to aqueous 0.5 and 2.25 M Bu4NBr, the meta and para polar effects, the ortho inductive and resonance effects in alkaline hydrolysis of phenyl esters of substituted benzoic acids, became stronger nearly to the same extent as found for alkaline hydrolysis of C6H5CO2C6H4-X. The steric term of ortho-substituted esters was almost independent of the media considered. The rate constants of alkaline hydrolysis of ortho-, meta- and para-substituted phenyl benzoates (X-C6H4CO2C6H5, C6H5CO2C6H4-X) and alkyl benzoates, C6H5CO2R, in water, 0.5 and 2.25 M Bu4NBr were correlated with the corresponding IR stretching frequencies of carbonyl group, (ΔνCO)X.

scholarly journals Spin-one dark matter and gamma ray signals from the galactic center

2020 ◽  
Vol 2020 (8) ◽  
Author(s):  
H. Hernández-Arellano ◽  
M. Napsuciale ◽  
S. Rodríguez
Keyword(s):  
Dark Matter ◽  
Cross Section ◽  
Gamma Ray ◽  
Galactic Center ◽  
Photon Emission ◽  
Scalar Coupling ◽  
Initial State ◽  
Internal Bremsstrahlung ◽  
Resonance Effects ◽  
State Radiation

Abstract In this work we study the possibility that the gamma ray excess (GRE) at the Milky Way galactic center come from the annihilation of dark matter with a (1, 0) ⊕ (0, 1) space-time structure (spin-one dark matter, SODM). We calculate the production of prompt photons from initial state radiation, internal bremsstrahlung, final state radiation including the emission from the decay products of the μ, τ or hadronization of quarks. Next we study the delayed photon emission from the inverse Compton scattering (ICS) of electrons (produced directly or in the prompt decay of μ, τ leptons or in the hadronization of quarks produced in the annihilation of SODM) with the cosmic microwave background or starlight. All these mechanisms yield significant contributions only for Higgs resonant exchange, i.e. for M ≈ MH /2, and the results depend on the Higgs scalar coupling to SODM, gs. The dominant mechanism at the GRE bump is the prompt photon production in the hadronization of b quarks produced in $$ \overline{D}D\to \overline{b}b $$ D ¯ D → b ¯ b , whereas the delayed photon emission from the ICS of electrons coming from the hadronization of b quarks produced in the same reaction dominates at low energies (ω < 0.3 GeV ) and prompt photons from c and τ , as well as from internal bremsstrahlung, yield competitive contributions at the end point of the spectrum (ω ≥ 30 GeV ). Taking into account all these contributions, our results for photons produced in the annihilation of SODM are in good agreement with the GRE data for gs ∈ [0.98, 1.01] × 10−3 and M ∈ [62.470, 62.505] GeV . We study the consistency of the corresponding results for the dark matter relic density, the spin-independent dark matter-nucleon cross-section σp and the cross section for the annihilation of dark matter into $$ \overline{b}b $$ b ¯ b , τ+τ−, μ+μ− and γγ, taking into account the Higgs resonance effects, finding consistent results in all cases.

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