Low temperature gas phase and matrix studies of the C6H3F3+ and C6H3Cl3+ radical cations

1980 ◽  
Vol 73 (5) ◽  
pp. 2063-2068 ◽  
Author(s):  
V. E. Bondybey ◽  
T. J. Sears ◽  
J. H. English ◽  
Terry A. Miller
Keyword(s):  
Low Temperature ◽  
Gas Phase ◽  
Radical Cations

Reactivity Trends in the Gas Phase Addition of Acetylene to N-protonated Aryl Radical Cations

2020 ◽  
Author(s):  
Oisin Shiels ◽  
P. D. Kelly ◽  
Cameron C. Bright ◽  
Berwyck L. J. Poad ◽  
Stephen Blanksby ◽  
...  
Keyword(s):  
Gas Phase ◽  
Ion Trap ◽  
Radical Cations ◽  
Rate Coefficients ◽  
Similar Process ◽  
Ion Molecule Reactions ◽  
Aromatic Radicals ◽  
Polycyclic Aromatic ◽  
Gas Phase Ion ◽  
Type Radical

<div> <div> <div> <p>A key step in gas-phase polycyclic aromatic hydrocarbon (PAH) formation involves the addition of acetylene (or other alkyne) to σ-type aromatic radicals, with successive additions yielding more complex PAHs. A similar process can happen for N- containing aromatics. In cold diffuse environments, such as the interstellar medium, rates of radical addition may be enhanced when the σ-type radical is charged. This paper investigates the gas-phase ion-molecule reactions of acetylene with nine aromatic distonic σ-type radical cations derived from pyridinium (Pyr), anilinium (Anl) and benzonitrilium (Bzn) ions. Three isomers are studied in each case (radical sites at the ortho, meta and para positions). Using a room temperature ion trap, second-order rate coefficients, product branching ratios and reaction efficiencies are reported. </p> </div> </div> </div>

Aqueous Benzene Oxidation in Low-Temperature Plasma of Pulsed Corona Discharge

2016 ◽  
Vol 19 (2) ◽  
Author(s):  
Iakov Kornev ◽  
Sergei Preis
Keyword(s):  
Low Temperature ◽  
Corona Discharge ◽  
Gas Phase ◽  
Pulse Repetition Frequency ◽  
Repetition Frequency ◽  
Pulse Repetition ◽  
Benzene Oxidation ◽  
Low Temperature Plasma ◽  
Temperature Plasma ◽  
Pulsed Corona

AbstractWastewaters polluted with non-biodegradable volatile organic compounds (VOCs), such as aromatic substances, present a growing problem meeting no adequately affordable technological response. Low-temperature plasma generated in the gas-phase pulsed corona discharge (PCD) presents competitive advanced oxidation technology in abatement of various classes of pollutants, although the process parameters, the pulse repetition frequency and the liquid spray rate, require optimization. The experimental research into aqueous benzene oxidation with PCD was undertaken to establish the impact of the parameters to the energy efficiency. The oxidation reaction was found under the experimental conditions to mostly proceed in the gas phase showing little influence of the pulse repetition frequency and the gas-liquid contact surface. Oxidation of benzene and, presumably, other volatile pollutants in the volume of PCD reactor compartment presents an effective strategy of aqueous VOCs abatement.

Low-temperature study of radical cations of quadricyclane and norbornadiene in Na-ZSM-5 zeolites

1994 ◽  
Vol 218 (5-6) ◽  
pp. 485-491 ◽  
Author(s):  
K.R. Cromack ◽  
D.W. Werst ◽  
M.V. Barnabas ◽  
A.D. Trifunac
Keyword(s):  
Low Temperature ◽  
Radical Cations ◽  
Temperature Study
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